Scalable continuous solvo-jet process for ZIF-8 nanoparticles

Han Seul Choi; Seung Joon Lee; Youn Sang Bae; Suk Jin Choung; Sang Hyuk Im; Jinsoo Kim

doi:10.1016/j.cej.2014.12.068

Scalable continuous solvo-jet process for ZIF-8 nanoparticles

Han Seul Choi, Seung Joon Lee, Youn Sang Bae, Suk Jin Choung, Sang Hyuk Im, Jinsoo Kim

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Conventionally, ZIF-8 particles have been prepared in batch solvothermal reactors, imposing limitations on the stability to achieve large-scale, rapid, and reproducible synthesis. In this study, ZIF-8 nanoparticles with narrow particle size distribution were produced continuously in a tubular reactor by a novel solvo-jet process, which combined solvothermal reaction for nucleation and vaporization-induced solid-liquid reaction for crystal growth and facet development. The size and morphology of the product ZIF-8 nanoparticles were significantly affected by the reaction temperature and residence time. With increasing reaction temperature from 120. °C to 180. °C, the average particle size decreased from 155. nm to 35. nm. The mechanism of crystal formation by continuous solvo-jet process was studied. Furthermore, gas separation properties of the product ZIF-8 nanoparticles were investigated by the adsorption of various gases.

Original language	English
Pages (from-to)	56-63
Number of pages	8
Journal	Chemical Engineering Journal
Volume	266
DOIs	https://doi.org/10.1016/j.cej.2014.12.068
Publication status	Published - 2015 Apr 5

Keywords

Continuous process
Gas adsorption
Solvothermal process
Tubular reactor
ZIF-8

ASJC Scopus subject areas

Chemistry(all)
Environmental Chemistry
Chemical Engineering(all)
Industrial and Manufacturing Engineering

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title = "Scalable continuous solvo-jet process for ZIF-8 nanoparticles",

abstract = "Conventionally, ZIF-8 particles have been prepared in batch solvothermal reactors, imposing limitations on the stability to achieve large-scale, rapid, and reproducible synthesis. In this study, ZIF-8 nanoparticles with narrow particle size distribution were produced continuously in a tubular reactor by a novel solvo-jet process, which combined solvothermal reaction for nucleation and vaporization-induced solid-liquid reaction for crystal growth and facet development. The size and morphology of the product ZIF-8 nanoparticles were significantly affected by the reaction temperature and residence time. With increasing reaction temperature from 120. °C to 180. °C, the average particle size decreased from 155. nm to 35. nm. The mechanism of crystal formation by continuous solvo-jet process was studied. Furthermore, gas separation properties of the product ZIF-8 nanoparticles were investigated by the adsorption of various gases.",

keywords = "Continuous process, Gas adsorption, Solvothermal process, Tubular reactor, ZIF-8",

author = "Choi, {Han Seul} and Lee, {Seung Joon} and Bae, {Youn Sang} and Choung, {Suk Jin} and Im, {Sang Hyuk} and Jinsoo Kim",

note = "Funding Information: This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2013R1A2A2A01014540 ). Publisher Copyright: {\textcopyright} 2014 Elsevier B.V. Copyright: Copyright 2015 Elsevier B.V., All rights reserved.",

year = "2015",

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day = "5",

doi = "10.1016/j.cej.2014.12.068",

language = "English",

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AU - Choi, Han Seul

AU - Lee, Seung Joon

AU - Bae, Youn Sang

AU - Choung, Suk Jin

AU - Im, Sang Hyuk

AU - Kim, Jinsoo

N1 - Funding Information: This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2013R1A2A2A01014540 ). Publisher Copyright: © 2014 Elsevier B.V. Copyright: Copyright 2015 Elsevier B.V., All rights reserved.

PY - 2015/4/5

Y1 - 2015/4/5

N2 - Conventionally, ZIF-8 particles have been prepared in batch solvothermal reactors, imposing limitations on the stability to achieve large-scale, rapid, and reproducible synthesis. In this study, ZIF-8 nanoparticles with narrow particle size distribution were produced continuously in a tubular reactor by a novel solvo-jet process, which combined solvothermal reaction for nucleation and vaporization-induced solid-liquid reaction for crystal growth and facet development. The size and morphology of the product ZIF-8 nanoparticles were significantly affected by the reaction temperature and residence time. With increasing reaction temperature from 120. °C to 180. °C, the average particle size decreased from 155. nm to 35. nm. The mechanism of crystal formation by continuous solvo-jet process was studied. Furthermore, gas separation properties of the product ZIF-8 nanoparticles were investigated by the adsorption of various gases.

AB - Conventionally, ZIF-8 particles have been prepared in batch solvothermal reactors, imposing limitations on the stability to achieve large-scale, rapid, and reproducible synthesis. In this study, ZIF-8 nanoparticles with narrow particle size distribution were produced continuously in a tubular reactor by a novel solvo-jet process, which combined solvothermal reaction for nucleation and vaporization-induced solid-liquid reaction for crystal growth and facet development. The size and morphology of the product ZIF-8 nanoparticles were significantly affected by the reaction temperature and residence time. With increasing reaction temperature from 120. °C to 180. °C, the average particle size decreased from 155. nm to 35. nm. The mechanism of crystal formation by continuous solvo-jet process was studied. Furthermore, gas separation properties of the product ZIF-8 nanoparticles were investigated by the adsorption of various gases.

KW - Continuous process

KW - Gas adsorption

KW - Solvothermal process

KW - Tubular reactor

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Scalable continuous solvo-jet process for ZIF-8 nanoparticles

Abstract

Keywords

ASJC Scopus subject areas

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