Second-order nonlinear optical properties of novel α-methylstyrene copolymers containing the organo-boron salt dye chromophore in the side chain

Dong Hoon Choi, S. Y. Song, S. J. Lim, S. Y. Park, N. Kim

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

We synthesized α-methylstyrene copolymers containing the organic salt chromophore and investigated their second-order nonlinear optical properties in terms of the linear electro-optic coefficient, r33. The measured electro-optic coefficients of poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1-dimethyl-m-isopropenyl) benzyl])carbamate-comethylmethacrylate (POLYMER I & II), and poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1-dimethyl-m-isopropenyl)benzyl]]carbamate-co-N-vinylcarba zole (POLYMER III) were determined around 30-40 pm/V at 632 nm wavelength. The observed temporal stabilities of linear electro-optic coefficients of these copolymers were observed much better than that of guest-host system or other NLO side chain polymers due to their outstanding physical properties.

Original languageEnglish
Pages (from-to)1731-1732
Number of pages2
JournalSynthetic Metals
Volume71
Issue number1-3
Publication statusPublished - 1995 Apr 1
Externally publishedYes

Fingerprint

Boron
Chromophores
Electrooptical effects
chromophores
electro-optics
copolymers
Borates
boron
Coloring Agents
Carbamates
Copolymers
Dyes
Optical properties
Salts
dyes
salts
borates
optical properties
coefficients
Polymers

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Metals and Alloys
  • Materials Chemistry
  • Electronic, Optical and Magnetic Materials
  • Mechanics of Materials
  • Mechanical Engineering
  • Polymers and Plastics

Cite this

Second-order nonlinear optical properties of novel α-methylstyrene copolymers containing the organo-boron salt dye chromophore in the side chain. / Choi, Dong Hoon; Song, S. Y.; Lim, S. J.; Park, S. Y.; Kim, N.

In: Synthetic Metals, Vol. 71, No. 1-3, 01.04.1995, p. 1731-1732.

Research output: Contribution to journalArticle

@article{13d1a98334134591bc83aee13f17e97f,
title = "Second-order nonlinear optical properties of novel α-methylstyrene copolymers containing the organo-boron salt dye chromophore in the side chain",
abstract = "We synthesized α-methylstyrene copolymers containing the organic salt chromophore and investigated their second-order nonlinear optical properties in terms of the linear electro-optic coefficient, r33. The measured electro-optic coefficients of poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1-dimethyl-m-isopropenyl) benzyl])carbamate-comethylmethacrylate (POLYMER I & II), and poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1-dimethyl-m-isopropenyl)benzyl]]carbamate-co-N-vinylcarba zole (POLYMER III) were determined around 30-40 pm/V at 632 nm wavelength. The observed temporal stabilities of linear electro-optic coefficients of these copolymers were observed much better than that of guest-host system or other NLO side chain polymers due to their outstanding physical properties.",
author = "Choi, {Dong Hoon} and Song, {S. Y.} and Lim, {S. J.} and Park, {S. Y.} and N. Kim",
year = "1995",
month = "4",
day = "1",
language = "English",
volume = "71",
pages = "1731--1732",
journal = "Synthetic Metals",
issn = "0379-6779",
publisher = "Elsevier BV",
number = "1-3",

}

TY - JOUR

T1 - Second-order nonlinear optical properties of novel α-methylstyrene copolymers containing the organo-boron salt dye chromophore in the side chain

AU - Choi, Dong Hoon

AU - Song, S. Y.

AU - Lim, S. J.

AU - Park, S. Y.

AU - Kim, N.

PY - 1995/4/1

Y1 - 1995/4/1

N2 - We synthesized α-methylstyrene copolymers containing the organic salt chromophore and investigated their second-order nonlinear optical properties in terms of the linear electro-optic coefficient, r33. The measured electro-optic coefficients of poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1-dimethyl-m-isopropenyl) benzyl])carbamate-comethylmethacrylate (POLYMER I & II), and poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1-dimethyl-m-isopropenyl)benzyl]]carbamate-co-N-vinylcarba zole (POLYMER III) were determined around 30-40 pm/V at 632 nm wavelength. The observed temporal stabilities of linear electro-optic coefficients of these copolymers were observed much better than that of guest-host system or other NLO side chain polymers due to their outstanding physical properties.

AB - We synthesized α-methylstyrene copolymers containing the organic salt chromophore and investigated their second-order nonlinear optical properties in terms of the linear electro-optic coefficient, r33. The measured electro-optic coefficients of poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1-dimethyl-m-isopropenyl) benzyl])carbamate-comethylmethacrylate (POLYMER I & II), and poly [1-[(N-ethylenepiperazyl)-stilbazolium tetraphenyl borate]-N-[(1,1-dimethyl-m-isopropenyl)benzyl]]carbamate-co-N-vinylcarba zole (POLYMER III) were determined around 30-40 pm/V at 632 nm wavelength. The observed temporal stabilities of linear electro-optic coefficients of these copolymers were observed much better than that of guest-host system or other NLO side chain polymers due to their outstanding physical properties.

UR - http://www.scopus.com/inward/record.url?scp=0029289228&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0029289228&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0029289228

VL - 71

SP - 1731

EP - 1732

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

IS - 1-3

ER -