Selective CO2 adsorption and proton conductivity in the two-dimensional Zn(ii) framework with protruded water molecules and flexible ether linkers

Won Ju Phang, Woo Ram Lee, Kicheon Yoo, Bongsoo Kim, Chang Seop Hong

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

A two-dimensional (2D) Zn(ii) metal-organic framework with flexible aryl ether linkers and water molecules exposed to the pores was prepared. The supramolecular three-dimensional (3D) network is generated by the presence of extensive π-π contacts, which could be responsible for gas uptake. The water molecules and oxygen atoms from the flexible linkers create a polar environment within the integrated framework, leading to simultaneous selective CO2 adsorption and proton conductivity in the two-dimensional Zn(ii) framework.

Original languageEnglish
Pages (from-to)7850-7853
Number of pages4
JournalDalton Transactions
Volume42
Issue number22
DOIs
Publication statusPublished - 2013 Jun 14

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Proton conductivity
Ether
Adsorption
Protons
Molecules
Water
Gases
Metals
Oxygen
Atoms

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Selective CO2 adsorption and proton conductivity in the two-dimensional Zn(ii) framework with protruded water molecules and flexible ether linkers. / Phang, Won Ju; Lee, Woo Ram; Yoo, Kicheon; Kim, Bongsoo; Hong, Chang Seop.

In: Dalton Transactions, Vol. 42, No. 22, 14.06.2013, p. 7850-7853.

Research output: Contribution to journalArticle

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