Self-assembled nanostructures of block copolymers on random copolymer brush

Bong Hoon Kim, Chong Min Koo, Seong Jun Jeong, Dong Ok Shin, Sang Ouk Kim

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

We synthesized the polymer brushes by conventional free radical polymerization and investigated the morphology evolution of block copolymer nanostructure on the brush treated surfaces. Our simple approach utilized a functionalized free radical initiator to add hydroxyl group to a chain end and an excess amount of a chain transfer agent to control the molecular weights of the brushes. The synthesized polymer brushes had narrow molecular weight distribution as well as hydroxyl end group and were successfully grafted onto silicon oxide layer by simple spin-coating and annealing process. The orientation of poly(styrene-block-methyl methacrylate)s (PS-b-PMMAs) coated on the brush grafted surface was finely controlled by the surface modification by polymer brushes.

Original languageEnglish
Title of host publicationAdvances in Nanomaterials and Processing - IUMRS - ICA - 2006 International Conference in Asia
PublisherTrans Tech Publications Ltd
Pages579-582
Number of pages4
EditionPART 1
ISBN (Print)3908451310, 9783908451310
Publication statusPublished - 2007 Jan 1
Externally publishedYes
EventIUMRS International Conference in Asia 2006, IUMRS-ICA 2006 - Jeju, Korea, Republic of
Duration: 2006 Sep 102006 Sep 14

Publication series

NameSolid State Phenomena
NumberPART 1
Volume124-126
ISSN (Print)1012-0394

Other

OtherIUMRS International Conference in Asia 2006, IUMRS-ICA 2006
CountryKorea, Republic of
CityJeju
Period06/9/1006/9/14

Fingerprint

brushes
Brushes
block copolymers
Block copolymers
Nanostructures
copolymers
Copolymers
Polymers
Hydroxyl Radical
free radicals
molecular weight
polymers
Silicon oxides
Spin coating
initiators
Molecular weight distribution
Free radical polymerization
silicon oxides
Free radicals
Free Radicals

Keywords

  • Block copolymer
  • Nanostructure
  • Polymer brush
  • Self-assembly

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Kim, B. H., Koo, C. M., Jeong, S. J., Shin, D. O., & Kim, S. O. (2007). Self-assembled nanostructures of block copolymers on random copolymer brush. In Advances in Nanomaterials and Processing - IUMRS - ICA - 2006 International Conference in Asia (PART 1 ed., pp. 579-582). (Solid State Phenomena; Vol. 124-126, No. PART 1). Trans Tech Publications Ltd.

Self-assembled nanostructures of block copolymers on random copolymer brush. / Kim, Bong Hoon; Koo, Chong Min; Jeong, Seong Jun; Shin, Dong Ok; Kim, Sang Ouk.

Advances in Nanomaterials and Processing - IUMRS - ICA - 2006 International Conference in Asia. PART 1. ed. Trans Tech Publications Ltd, 2007. p. 579-582 (Solid State Phenomena; Vol. 124-126, No. PART 1).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Kim, BH, Koo, CM, Jeong, SJ, Shin, DO & Kim, SO 2007, Self-assembled nanostructures of block copolymers on random copolymer brush. in Advances in Nanomaterials and Processing - IUMRS - ICA - 2006 International Conference in Asia. PART 1 edn, Solid State Phenomena, no. PART 1, vol. 124-126, Trans Tech Publications Ltd, pp. 579-582, IUMRS International Conference in Asia 2006, IUMRS-ICA 2006, Jeju, Korea, Republic of, 06/9/10.
Kim BH, Koo CM, Jeong SJ, Shin DO, Kim SO. Self-assembled nanostructures of block copolymers on random copolymer brush. In Advances in Nanomaterials and Processing - IUMRS - ICA - 2006 International Conference in Asia. PART 1 ed. Trans Tech Publications Ltd. 2007. p. 579-582. (Solid State Phenomena; PART 1).
Kim, Bong Hoon ; Koo, Chong Min ; Jeong, Seong Jun ; Shin, Dong Ok ; Kim, Sang Ouk. / Self-assembled nanostructures of block copolymers on random copolymer brush. Advances in Nanomaterials and Processing - IUMRS - ICA - 2006 International Conference in Asia. PART 1. ed. Trans Tech Publications Ltd, 2007. pp. 579-582 (Solid State Phenomena; PART 1).
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