Solid-state phosphorescence-to-fluorescence switching in a cyclometalated Ir(iii) complex containing an acid-labile chromophoric ancillary ligand: Implication for multimodal security printing

Dong Ryeol Whang, Youngmin You, Weon Sik Chae, Jeongyun Heo, Sehoon Kim, Soo Young Park

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

In this study, we have demonstrated the reconstruction of encrypted information by employing photoluminescence spectra and lifetimes of a phosphorescent Ir(III) complex (IrHBT). IrHBT was constructed on the basis of a heteroleptic structure comprising a fluorescent N^O ancillary ligand. From the viewpoint of information security, the transformation of the Ir(III) complex between phosphorescent and fluorescent states can be encoded with chemical/photoirradiation methods. Thin polymer films (poly(methylmethacrylate), PMMA) doped with IrHBT display long-lived emission typical of phosphorescence (λmax = 586 nm, τobs = 2.90 μs). Meanwhile, exposure to HCl vapor switches the emission to fluorescence (λ max = 514 nm, τobs = 1.53 ns) with drastic changes in both the photoluminescence color and lifetime. Security printing on paper impregnated with IrHBT or on a PMMA film containing IrHBT and photoacid generator (triphenylsulfonium triflate) enables the bimodal readout of photoluminescence color and lifetime.

Original languageEnglish
Pages (from-to)15433-15437
Number of pages5
JournalLangmuir
Volume28
Issue number44
DOIs
Publication statusPublished - 2012 Nov 6
Externally publishedYes

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ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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