Solid-state polymerization and characterization of a copolyamide based on adipic acid, 1,4-butanediamine, and 2,5-furandicarboxylic acid

Yohana Kurnia Endah, Sang Hoon Han, Jae Hoon Kim, Nak Kyoon Kim, Woo Nyon Kim, Hong Shik Lee, Hyunjoo Lee

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

2,5-Furandicarboxylic acid (FDCA) is a promising biobased alternative material to terephthalic acid. In this study, three types of poly(butylene adipamide) (PA-4,6) containing 10, 20, and 30 mol % of poly(butylene-2,5-furandicarboxylamide) (PA-4,F) were synthesized through consecutive prepolymerization and solid-state polymerization (SSP). The incorporation of a 10 mol % PA-4,F component into PA-4,6 resulted in slight increases in the intrinsic viscosity (IV) and glass-transition temperature (Tg) after 12 h of SSP at 220°C. When the SSP temperature and reaction time increased, IV increased proportionally. The highest IV value of 0.75 was obtained by 48 h of SSP at 240°C, whereas increases in the PA-4,F content to 20 and 30 mol % gave rise to decreases in IV, Tg, and melting temperature; this interrupted the increase in SSP temperature. The thermal decomposition temperature of the PA-4,F-incorporated polyamide was lower than that with PA-4,6 because of the lower thermal stability of the FDCA component.

Original languageEnglish
Article number43391
JournalJournal of Applied Polymer Science
Volume133
Issue number18
DOIs
Publication statusPublished - 2016 May 10

Fingerprint

Putrescine
Polymerization
Acids
Viscosity
Nylons
Polyamides
Temperature
Melting point
Pyrolysis
Thermodynamic stability
adipic acid
2,5-furandicarboxylic acid

Keywords

  • biopolymers and renewable polymers
  • synthesis and processing
  • thermal properties

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics
  • Surfaces, Coatings and Films
  • Chemistry(all)

Cite this

Solid-state polymerization and characterization of a copolyamide based on adipic acid, 1,4-butanediamine, and 2,5-furandicarboxylic acid. / Endah, Yohana Kurnia; Han, Sang Hoon; Kim, Jae Hoon; Kim, Nak Kyoon; Kim, Woo Nyon; Lee, Hong Shik; Lee, Hyunjoo.

In: Journal of Applied Polymer Science, Vol. 133, No. 18, 43391, 10.05.2016.

Research output: Contribution to journalArticle

Endah, Yohana Kurnia ; Han, Sang Hoon ; Kim, Jae Hoon ; Kim, Nak Kyoon ; Kim, Woo Nyon ; Lee, Hong Shik ; Lee, Hyunjoo. / Solid-state polymerization and characterization of a copolyamide based on adipic acid, 1,4-butanediamine, and 2,5-furandicarboxylic acid. In: Journal of Applied Polymer Science. 2016 ; Vol. 133, No. 18.
@article{4f4b6e1db0b449d28273b9b5750eb4cb,
title = "Solid-state polymerization and characterization of a copolyamide based on adipic acid, 1,4-butanediamine, and 2,5-furandicarboxylic acid",
abstract = "2,5-Furandicarboxylic acid (FDCA) is a promising biobased alternative material to terephthalic acid. In this study, three types of poly(butylene adipamide) (PA-4,6) containing 10, 20, and 30 mol {\%} of poly(butylene-2,5-furandicarboxylamide) (PA-4,F) were synthesized through consecutive prepolymerization and solid-state polymerization (SSP). The incorporation of a 10 mol {\%} PA-4,F component into PA-4,6 resulted in slight increases in the intrinsic viscosity (IV) and glass-transition temperature (Tg) after 12 h of SSP at 220°C. When the SSP temperature and reaction time increased, IV increased proportionally. The highest IV value of 0.75 was obtained by 48 h of SSP at 240°C, whereas increases in the PA-4,F content to 20 and 30 mol {\%} gave rise to decreases in IV, Tg, and melting temperature; this interrupted the increase in SSP temperature. The thermal decomposition temperature of the PA-4,F-incorporated polyamide was lower than that with PA-4,6 because of the lower thermal stability of the FDCA component.",
keywords = "biopolymers and renewable polymers, synthesis and processing, thermal properties",
author = "Endah, {Yohana Kurnia} and Han, {Sang Hoon} and Kim, {Jae Hoon} and Kim, {Nak Kyoon} and Kim, {Woo Nyon} and Lee, {Hong Shik} and Hyunjoo Lee",
year = "2016",
month = "5",
day = "10",
doi = "10.1002/app.43391",
language = "English",
volume = "133",
journal = "Journal of Applied Polymer Science",
issn = "0021-8995",
publisher = "John Wiley and Sons Inc.",
number = "18",

}

TY - JOUR

T1 - Solid-state polymerization and characterization of a copolyamide based on adipic acid, 1,4-butanediamine, and 2,5-furandicarboxylic acid

AU - Endah, Yohana Kurnia

AU - Han, Sang Hoon

AU - Kim, Jae Hoon

AU - Kim, Nak Kyoon

AU - Kim, Woo Nyon

AU - Lee, Hong Shik

AU - Lee, Hyunjoo

PY - 2016/5/10

Y1 - 2016/5/10

N2 - 2,5-Furandicarboxylic acid (FDCA) is a promising biobased alternative material to terephthalic acid. In this study, three types of poly(butylene adipamide) (PA-4,6) containing 10, 20, and 30 mol % of poly(butylene-2,5-furandicarboxylamide) (PA-4,F) were synthesized through consecutive prepolymerization and solid-state polymerization (SSP). The incorporation of a 10 mol % PA-4,F component into PA-4,6 resulted in slight increases in the intrinsic viscosity (IV) and glass-transition temperature (Tg) after 12 h of SSP at 220°C. When the SSP temperature and reaction time increased, IV increased proportionally. The highest IV value of 0.75 was obtained by 48 h of SSP at 240°C, whereas increases in the PA-4,F content to 20 and 30 mol % gave rise to decreases in IV, Tg, and melting temperature; this interrupted the increase in SSP temperature. The thermal decomposition temperature of the PA-4,F-incorporated polyamide was lower than that with PA-4,6 because of the lower thermal stability of the FDCA component.

AB - 2,5-Furandicarboxylic acid (FDCA) is a promising biobased alternative material to terephthalic acid. In this study, three types of poly(butylene adipamide) (PA-4,6) containing 10, 20, and 30 mol % of poly(butylene-2,5-furandicarboxylamide) (PA-4,F) were synthesized through consecutive prepolymerization and solid-state polymerization (SSP). The incorporation of a 10 mol % PA-4,F component into PA-4,6 resulted in slight increases in the intrinsic viscosity (IV) and glass-transition temperature (Tg) after 12 h of SSP at 220°C. When the SSP temperature and reaction time increased, IV increased proportionally. The highest IV value of 0.75 was obtained by 48 h of SSP at 240°C, whereas increases in the PA-4,F content to 20 and 30 mol % gave rise to decreases in IV, Tg, and melting temperature; this interrupted the increase in SSP temperature. The thermal decomposition temperature of the PA-4,F-incorporated polyamide was lower than that with PA-4,6 because of the lower thermal stability of the FDCA component.

KW - biopolymers and renewable polymers

KW - synthesis and processing

KW - thermal properties

UR - http://www.scopus.com/inward/record.url?scp=84958108963&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84958108963&partnerID=8YFLogxK

U2 - 10.1002/app.43391

DO - 10.1002/app.43391

M3 - Article

AN - SCOPUS:84968324801

VL - 133

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

SN - 0021-8995

IS - 18

M1 - 43391

ER -