Solubility of carbon dioxide in strongly basic ionic liquid

Jun Kyung Sung; Sung Hyun Kim; Minserk Cheong; Ilhyun Baek

doi:10.5012/bkcs.2010.31.10.2797

Solubility of carbon dioxide in strongly basic ionic liquid

Jun Kyung Sung, Sung Hyun Kim, Minserk Cheong, Ilhyun Baek

Honorary professors

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

For the purpose of developing advanced new absorbents for carbon dioxide, ionic liquids (ILs) are considered as alternative materials due to their superior properties to conventional organic solvents. Since low CO₂ solubility in ionic liquids is a major concern for their application as absorbents, it is essential to focus on improving CO₂ absorbing capability of ILs. In this paper, strongly basic ionic liquids, namely [Cn-mim]OPh (n = 2, 4, 6), have been synthesized and studied over a wide range of temperature and pressure changes. [Cn-mim]OPh can be easily synthesized from corresponding [Cn-mim]Cl and sodium phenoxide and has been found to be good CO₂ absorbents.

Original language	English
Pages (from-to)	2797-2800
Number of pages	4
Journal	Bulletin of the Korean Chemical Society
Volume	31
Issue number	10
DOIs	https://doi.org/10.5012/bkcs.2010.31.10.2797
Publication status	Published - 2010 Oct 20

Keywords

CO solubility
Carbon dioxide capture
Phenolate-based ionic liquid
Strongly basic ionic liquid

ASJC Scopus subject areas

Chemistry(all)

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abstract = "For the purpose of developing advanced new absorbents for carbon dioxide, ionic liquids (ILs) are considered as alternative materials due to their superior properties to conventional organic solvents. Since low CO2 solubility in ionic liquids is a major concern for their application as absorbents, it is essential to focus on improving CO2 absorbing capability of ILs. In this paper, strongly basic ionic liquids, namely [Cn-mim]OPh (n = 2, 4, 6), have been synthesized and studied over a wide range of temperature and pressure changes. [Cn-mim]OPh can be easily synthesized from corresponding [Cn-mim]Cl and sodium phenoxide and has been found to be good CO2 absorbents.",

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AU - Sung, Jun Kyung

AU - Kim, Sung Hyun

AU - Cheong, Minserk

AU - Baek, Ilhyun

PY - 2010/10/20

Y1 - 2010/10/20

N2 - For the purpose of developing advanced new absorbents for carbon dioxide, ionic liquids (ILs) are considered as alternative materials due to their superior properties to conventional organic solvents. Since low CO2 solubility in ionic liquids is a major concern for their application as absorbents, it is essential to focus on improving CO2 absorbing capability of ILs. In this paper, strongly basic ionic liquids, namely [Cn-mim]OPh (n = 2, 4, 6), have been synthesized and studied over a wide range of temperature and pressure changes. [Cn-mim]OPh can be easily synthesized from corresponding [Cn-mim]Cl and sodium phenoxide and has been found to be good CO2 absorbents.

AB - For the purpose of developing advanced new absorbents for carbon dioxide, ionic liquids (ILs) are considered as alternative materials due to their superior properties to conventional organic solvents. Since low CO2 solubility in ionic liquids is a major concern for their application as absorbents, it is essential to focus on improving CO2 absorbing capability of ILs. In this paper, strongly basic ionic liquids, namely [Cn-mim]OPh (n = 2, 4, 6), have been synthesized and studied over a wide range of temperature and pressure changes. [Cn-mim]OPh can be easily synthesized from corresponding [Cn-mim]Cl and sodium phenoxide and has been found to be good CO2 absorbents.

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KW - Carbon dioxide capture

KW - Phenolate-based ionic liquid

KW - Strongly basic ionic liquid

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