TY - JOUR
T1 - Solution-processed fabrication of superhydrophobic hierarchical zinc oxide nanostructures via nanotransfer printing and hydrothermal growth
AU - Hong, Sung Hoon
AU - Kim, Mi Hyun
AU - Yun, Hye Won
AU - Paik, Taejong
AU - Lee, Heon
N1 - Funding Information:
This work was financially supported by the Pioneer Research Center Program through the National Research Foundation of Korea, funded by the Ministry of Science, ICT & Future Planning ( NRF-2013M3C1A3063046 ). This research was supported by Chung-Ang University Research Grants in 2015.
PY - 2017/12/15
Y1 - 2017/12/15
N2 - In this report, we present a solution-based process to fabricate hierarchical ZnO nanostructures by a sequential nanoimprint process and hydrothermal reaction. Micro- or mesoscale ZnO patterns are first fabricated by solution-processed nanotransfer printing using colloidal ZnO nanoparticles. Nano-scale ZnO nanorods are then hydrothermally grown on the surface of microstructures to fabricate the hierarchical architectures. The ZnO-based hierarchical structures exhibited superior superhydrophobic properties with very small sliding angle (contact angle > 150°, sliding angle < 4°). A solution-based process using mild chemical reagents enables ZnO hierarchical structure to be fabricated on various types of substrates, including Si, glass, flexible polymer substrates, metal foils, curved surfaces, and even on the surface of LED devices, without significant damage to the substrate. This ability indicates that this fabrication method of superhydrophobic hierarchical surfaces can be potentially utilized to fabricate self-cleaning surfaces for many industrial applications, such as solar cell panels, building materials, and electronic devices.
AB - In this report, we present a solution-based process to fabricate hierarchical ZnO nanostructures by a sequential nanoimprint process and hydrothermal reaction. Micro- or mesoscale ZnO patterns are first fabricated by solution-processed nanotransfer printing using colloidal ZnO nanoparticles. Nano-scale ZnO nanorods are then hydrothermally grown on the surface of microstructures to fabricate the hierarchical architectures. The ZnO-based hierarchical structures exhibited superior superhydrophobic properties with very small sliding angle (contact angle > 150°, sliding angle < 4°). A solution-based process using mild chemical reagents enables ZnO hierarchical structure to be fabricated on various types of substrates, including Si, glass, flexible polymer substrates, metal foils, curved surfaces, and even on the surface of LED devices, without significant damage to the substrate. This ability indicates that this fabrication method of superhydrophobic hierarchical surfaces can be potentially utilized to fabricate self-cleaning surfaces for many industrial applications, such as solar cell panels, building materials, and electronic devices.
KW - Hierarchical nanostructures
KW - Hydrothermal growth
KW - Nanoimprinting
KW - Soft lithography
KW - Superhydrophobicity
KW - ZnO nanoparticles
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U2 - 10.1016/j.surfcoat.2017.10.022
DO - 10.1016/j.surfcoat.2017.10.022
M3 - Article
AN - SCOPUS:85032343174
VL - 331
SP - 189
EP - 195
JO - Surface and Coatings Technology
JF - Surface and Coatings Technology
SN - 0257-8972
ER -