Spectrophotometric Analysis of Phosphoric Acid Leakage in High-Temperature Phosphoric Acid-Doped Polybenzimidazole Membrane Fuel Cell Application

Seungyoon Han, Yeon Hun Jeong, Ju Hae Jung, Alina Begley, Euiji Choi, Sung Jong Yoo, Jong Hyun Jang, Hyoung Juhn Kim, SukWoo Nam, Jin Young Kim

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

High-temperature proton exchange membrane fuel cells (HT-PEMFCs) utilize a phosphoric acid- (PA-) doped polybenzimidazole (PBI) membrane as a polymer electrolyte. The PA concentration in the membrane can affect fuel cell performance, as a significant amount of PA can leak from the membrane electrode assembly (MEA) by dissolution in discharged water, which is a byproduct of cell operation. Spectrophotometric analysis of PA leakage in PA-doped polybenzimidazole membrane fuel cells is described here. This spectrophotometric analysis is based on measurement of absorption of an ion pair formed by phosphomolybdic anions and the cationoid color reagent. Different color reagents were tested based on PA detection sensitivity, stability of the formed color, and accuracy with respect to the amount of PA measured. This method allows for nondestructive analysis and monitoring of PA leakage during HT-PEMFCs operation.

Original languageEnglish
Article number5290510
JournalJournal of Sensors
Volume2016
DOIs
Publication statusPublished - 2016

Fingerprint

polybenzimidazole
phosphoric acid
Phosphoric acid
fuel cells
Fuel cells
leakage
membranes
Membranes
Proton exchange membrane fuel cells (PEMFC)
Color
color
Temperature
reagents
Byproducts
Dissolution
Negative ions
protons
Electrolytes
Electrodes
Monitoring

ASJC Scopus subject areas

  • Instrumentation
  • Electrical and Electronic Engineering
  • Control and Systems Engineering

Cite this

Spectrophotometric Analysis of Phosphoric Acid Leakage in High-Temperature Phosphoric Acid-Doped Polybenzimidazole Membrane Fuel Cell Application. / Han, Seungyoon; Jeong, Yeon Hun; Jung, Ju Hae; Begley, Alina; Choi, Euiji; Yoo, Sung Jong; Jang, Jong Hyun; Kim, Hyoung Juhn; Nam, SukWoo; Kim, Jin Young.

In: Journal of Sensors, Vol. 2016, 5290510, 2016.

Research output: Contribution to journalArticle

Han, Seungyoon ; Jeong, Yeon Hun ; Jung, Ju Hae ; Begley, Alina ; Choi, Euiji ; Yoo, Sung Jong ; Jang, Jong Hyun ; Kim, Hyoung Juhn ; Nam, SukWoo ; Kim, Jin Young. / Spectrophotometric Analysis of Phosphoric Acid Leakage in High-Temperature Phosphoric Acid-Doped Polybenzimidazole Membrane Fuel Cell Application. In: Journal of Sensors. 2016 ; Vol. 2016.
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AU - Choi, Euiji

AU - Yoo, Sung Jong

AU - Jang, Jong Hyun

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