Spin crossover in the cyanide-bridged Mo VMn III single-chain magnet containing Fe II cations

Jung Hee Yoon, Dae Won Ryu, Sang Yup Choi, Hyoung Chan Kim, Eui Kwan Koh, Jun Tao, Chang Seop Hong

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

A 1D Mo VMn III chain compound balanced by {Fe[HC(3,5-Me 2pz) 3] 2} 2+ dications was prepared. This complex displays a typical single-chain magnet character associated with the Mo VMn III chain and a spin crossover phenomenon arising from cationic Fe(ii) subunits. The spin crossover behavior tends to slightly affect single-chain magnetic properties at low temperature.

Original languageEnglish
Pages (from-to)10416-10418
Number of pages3
JournalChemical Communications
Volume47
Issue number37
DOIs
Publication statusPublished - 2011 Oct 7

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ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

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