Abstract
A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr2+ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca2+ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.
| Original language | English |
|---|---|
| Pages (from-to) | 620-622 |
| Number of pages | 3 |
| Journal | Bulletin of the Korean Chemical Society |
| Volume | 29 |
| Issue number | 3 |
| Publication status | Published - 2008 Mar 20 |
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Keywords
- Calixarene
- Ion recognition
- Strontium
- Thiacalixarene
- Voltammetry
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Sr2+ ion selective p-tert-butylthiacalix[4]arene bearing two distal amide units. / Tae, Hyun Kim; Kim, Hasuck; Joung, Hae Lee; Kim, Jong Seung.
In: Bulletin of the Korean Chemical Society, Vol. 29, No. 3, 20.03.2008, p. 620-622.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Sr2+ ion selective p-tert-butylthiacalix[4]arene bearing two distal amide units
AU - Tae, Hyun Kim
AU - Kim, Hasuck
AU - Joung, Hae Lee
AU - Kim, Jong Seung
PY - 2008/3/20
Y1 - 2008/3/20
N2 - A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr2+ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca2+ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.
AB - A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr2+ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca2+ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.
KW - Calixarene
KW - Ion recognition
KW - Strontium
KW - Thiacalixarene
KW - Voltammetry
UR - http://www.scopus.com/inward/record.url?scp=41549129347&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=41549129347&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:41549129347
VL - 29
SP - 620
EP - 622
JO - Bulletin of the Korean Chemical Society
JF - Bulletin of the Korean Chemical Society
SN - 0253-2964
IS - 3
ER -