Steam reforming of simulated biogas over plate Ni-Cr catalysts: Influence of pre-oxidation on catalytic activity

Quynh Thi Phuong Bui, Yongmin Kim, Sung Pil Yoon, Jonghee Han, Hyung Chul Ham, SukWoo Nam, Chang Won Yoon

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The activity and stability of NiCr plate catalysts were significantly enhanced by a pretreatment process involving pre-oxidation at ≥600°C with subsequent reduction at 700°C. Analytical techniques including SEM, TEM, and XPS-depth profiling studies revealed that the pretreatment induced surface reconstruction in the bulk NiCr material generating new Ni sites with improved activity. The catalytic activity was highly dependent upon the oxidation temperature. In addition to the creation of novel Ni sites, chromium oxide acted as a structural promoter to suppress sintering of the Ni active sites. Activation of the NiCr plate catalyst via pretreatment at 700°C resulted in improved stability for biogas reforming reactions over a period of 100h. Moreover, the stability of the reforming catalyst was sustained over 100h with a steam/CH4 ratio of ≥1.5. The influences of temperature, inlet H2O/CH4 ratio, and CH4/CO2 ratios on the steam reforming of biogas were further studied.

Original languageEnglish
Pages (from-to)335-344
Number of pages10
JournalApplied Catalysis B: Environmental
Volume166-167
DOIs
Publication statusPublished - 2015 May 1

Fingerprint

Biofuels
Steam reforming
Biogas
biogas
Catalyst activity
catalyst
Reforming reactions
oxidation
Oxidation
Catalysts
Surface reconstruction
Depth profiling
Steam
X-ray spectroscopy
chromium
transmission electron microscopy
analytical method
Chromium
Sintering
X ray photoelectron spectroscopy

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology
  • Environmental Science(all)

Cite this

Steam reforming of simulated biogas over plate Ni-Cr catalysts : Influence of pre-oxidation on catalytic activity. / Bui, Quynh Thi Phuong; Kim, Yongmin; Yoon, Sung Pil; Han, Jonghee; Ham, Hyung Chul; Nam, SukWoo; Yoon, Chang Won.

In: Applied Catalysis B: Environmental, Vol. 166-167, 01.05.2015, p. 335-344.

Research output: Contribution to journalArticle

Bui, Quynh Thi Phuong ; Kim, Yongmin ; Yoon, Sung Pil ; Han, Jonghee ; Ham, Hyung Chul ; Nam, SukWoo ; Yoon, Chang Won. / Steam reforming of simulated biogas over plate Ni-Cr catalysts : Influence of pre-oxidation on catalytic activity. In: Applied Catalysis B: Environmental. 2015 ; Vol. 166-167. pp. 335-344.
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