Structural and electrochemical properties of LiNi0.7Co 0.15Mn0.15O2 thin film prepared by high frequency hybrid direct current and radio frequency magnetron sputtering

Youngmin Chung, Ho Young Park, Si Hyoung Oh, Dong Young Yoon, Sang Wan Jin, Dong Yoon Jang, Jang Myoun Ko, Won Il Cho, Seong Rae Lee

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A LiNi0.7Co0.15Mn0.15O2 thin film cathode has been successfully prepared by hybrid direct current - radio frequency magnetron sputtering onto glass substrate from the LiNi 0.7Co0.15Mn0.15O2 target and post-annealed by the rapid thermal annealing process. Its structure and morphology were characterized by X-ray diffraction, and scanning electron microscopy while its chemical compositions were confirmed with the inductively coupled plasma atomic absorption spectrophotometer, Raman spectroscopy, Auger electron spectroscopy, and glow discharge spectrometer. Its electrochemical properties were measured by galvanostatic charge - discharge test and cyclic voltammetry. First discharge capacity of 73 μAh cm-2 μm -1 was obtained from a half cell with the LiNi0.7Co 0.15Mn0.15O2 thin film cathode and lithium metal anode in the potential range of 4.3 ~ 2.5 V at 30 μA and its coulombic efficiency was more than 99 %.

Original languageEnglish
Pages (from-to)316-323
Number of pages8
JournalJournal of Electroceramics
Volume31
Issue number3-4
DOIs
Publication statusPublished - 2013 Dec

Keywords

  • Cathode
  • Glow discharge spectrometer
  • Hybrid direct current and radio frequency magnetron sputtering
  • LiNiCoMnO thin film
  • Thin film battery

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Mechanics of Materials
  • Electrical and Electronic Engineering
  • Materials Chemistry

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