Structural and magnetic properties of chemically synthesized Fe doped ZnO

Shalendra Kumar; Y. J. Kim; B. H. Koo; S. K. Sharma; J. M. Vargas; M. Knobel; S. Gautam; K. H. Chae; D. K. Kim; Y. K. Kim; C. G. Lee

doi:10.1063/1.3073933

Structural and magnetic properties of chemically synthesized Fe doped ZnO

Shalendra Kumar, Y. J. Kim, B. H. Koo, S. K. Sharma, J. M. Vargas, M. Knobel, S. Gautam, K. H. Chae, D. K. Kim, Y. K. Kim, C. G. Lee

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

73 Citations (Scopus)

Abstract

We report on the synthesis of Fe-doped ZnO with nominal composition of Zn0.99 Fe0.01 O by using a coprecipitation method. X-ray diffraction and selective area electron diffraction studies reveal a single phase wurtzite crystal structure without any secondary phase. Field emission transmission electron microscopy measurements infer that Zn0.99 Fe0.01 O have nanorod-type microstructures. Magnetic hysteresis measurement performed at different temperatures show that Zn0.99 Fe0.01 O exhibits a weak ferromagnetic behavior at room temperature. A detailed investigation of the electronic and local structure using O K -, Fe L3,2 near edge x-ray absorption fine structure suggests that Fe is substituting Zn in ZnO matrix and is in Fe3+ state.

Original language	English
Article number	07C520
Journal	Journal of Applied Physics
Volume	105
Issue number	7
DOIs	https://doi.org/10.1063/1.3073933
Publication status	Published - 2009

ASJC Scopus subject areas

Physics and Astronomy(all)

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10.1063/1.3073933

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@article{68188b020555454285ccfd725d9196fb,

title = "Structural and magnetic properties of chemically synthesized Fe doped ZnO",

abstract = "We report on the synthesis of Fe-doped ZnO with nominal composition of Zn0.99 Fe0.01 O by using a coprecipitation method. X-ray diffraction and selective area electron diffraction studies reveal a single phase wurtzite crystal structure without any secondary phase. Field emission transmission electron microscopy measurements infer that Zn0.99 Fe0.01 O have nanorod-type microstructures. Magnetic hysteresis measurement performed at different temperatures show that Zn0.99 Fe0.01 O exhibits a weak ferromagnetic behavior at room temperature. A detailed investigation of the electronic and local structure using O K -, Fe L3,2 near edge x-ray absorption fine structure suggests that Fe is substituting Zn in ZnO matrix and is in Fe3+ state.",

author = "Shalendra Kumar and Kim, {Y. J.} and Koo, {B. H.} and Sharma, {S. K.} and Vargas, {J. M.} and M. Knobel and S. Gautam and Chae, {K. H.} and Kim, {D. K.} and Kim, {Y. K.} and Lee, {C. G.}",

note = "Funding Information: This work was supported by the Korean Research Foundation Grant funded by the Korea Government (MOEHRD) (Grant No. KRF–2008–005–J02703). Authors (S.K.S. and M.K.) are very grateful to FAPESP and CNPq (Brazil) for providing financial support (Grant No. 06/06792-2). Authors (S.G. and K.H. Chae) are also thankful to KIST financial support (Grant No. 2V01320). This work is also supported in part by the National Research Laboratory Program (Grant No. M10500000105-05J000-10510).",

year = "2009",

doi = "10.1063/1.3073933",

language = "English",

volume = "105",

journal = "Journal of Applied Physics",

issn = "0021-8979",

publisher = "American Institute of Physics Publising LLC",

number = "7",

}

TY - JOUR

T1 - Structural and magnetic properties of chemically synthesized Fe doped ZnO

AU - Kumar, Shalendra

AU - Kim, Y. J.

AU - Koo, B. H.

AU - Sharma, S. K.

AU - Vargas, J. M.

AU - Knobel, M.

AU - Gautam, S.

AU - Chae, K. H.

AU - Kim, D. K.

AU - Kim, Y. K.

AU - Lee, C. G.

N1 - Funding Information: This work was supported by the Korean Research Foundation Grant funded by the Korea Government (MOEHRD) (Grant No. KRF–2008–005–J02703). Authors (S.K.S. and M.K.) are very grateful to FAPESP and CNPq (Brazil) for providing financial support (Grant No. 06/06792-2). Authors (S.G. and K.H. Chae) are also thankful to KIST financial support (Grant No. 2V01320). This work is also supported in part by the National Research Laboratory Program (Grant No. M10500000105-05J000-10510).

PY - 2009

Y1 - 2009

N2 - We report on the synthesis of Fe-doped ZnO with nominal composition of Zn0.99 Fe0.01 O by using a coprecipitation method. X-ray diffraction and selective area electron diffraction studies reveal a single phase wurtzite crystal structure without any secondary phase. Field emission transmission electron microscopy measurements infer that Zn0.99 Fe0.01 O have nanorod-type microstructures. Magnetic hysteresis measurement performed at different temperatures show that Zn0.99 Fe0.01 O exhibits a weak ferromagnetic behavior at room temperature. A detailed investigation of the electronic and local structure using O K -, Fe L3,2 near edge x-ray absorption fine structure suggests that Fe is substituting Zn in ZnO matrix and is in Fe3+ state.

AB - We report on the synthesis of Fe-doped ZnO with nominal composition of Zn0.99 Fe0.01 O by using a coprecipitation method. X-ray diffraction and selective area electron diffraction studies reveal a single phase wurtzite crystal structure without any secondary phase. Field emission transmission electron microscopy measurements infer that Zn0.99 Fe0.01 O have nanorod-type microstructures. Magnetic hysteresis measurement performed at different temperatures show that Zn0.99 Fe0.01 O exhibits a weak ferromagnetic behavior at room temperature. A detailed investigation of the electronic and local structure using O K -, Fe L3,2 near edge x-ray absorption fine structure suggests that Fe is substituting Zn in ZnO matrix and is in Fe3+ state.

UR - http://www.scopus.com/inward/record.url?scp=65249127672&partnerID=8YFLogxK

U2 - 10.1063/1.3073933

DO - 10.1063/1.3073933

M3 - Article

AN - SCOPUS:65249127672

VL - 105

JO - Journal of Applied Physics

JF - Journal of Applied Physics

SN - 0021-8979

IS - 7

M1 - 07C520

ER -

Structural and magnetic properties of chemically synthesized Fe doped ZnO

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