Structural Evolution of Chemically-Driven RuO<inf>2</inf> Nanowires and 3-Dimensional Design for Photo-Catalytic Applications

Joonmo Park, Jae Won Lee, Byeong Uk Ye, Sung He Chun, Sang Hoon Joo, Hyunwoong Park, Heon Lee, Hu Young Jeong, Myung Hwa Kim, Jeong Min Baik

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Growth mechanism of chemically-driven RuO<inf>2</inf> nanowires is explored and used to fabricate three-dimensional RuO<inf>2</inf> branched Au-TiO<inf>2</inf> nanowire electrodes for the photostable solar water oxidation. For the real time structural evolution during the nanowire growth, the amorphous RuO<inf>2</inf> precursors (Ru(OH)<inf>3</inf>·H<inf>2</inf>O) are heated at 180 °C, producing the RuO<inf>2</inf> nanoparticles with the tetragonal crystallographic structure and Ru enriched amorphous phases, observed through the in-situ synchrotron x-ray diffraction and the high-resolution transmission electron microscope images. Growth then proceeds by Ru diffusion to the nanoparticles, followed by the diffusion to the growing surface of the nanowire in oxygen ambient, supported by the nucleation theory. The RuO<inf>2</inf> branched Au-TiO<inf>2</inf> nanowire arrays shows a remarkable enhancement in the photocurrent density by approximately 60% and 200%, in the UV-visible and Visible region, respectively, compared with pristine TiO<inf>2</inf> nanowires. Furthermore, there is no significant decrease in the device's photoconductance with UV-visible illumination during 1 day, making it possible to produce oxygen gas without the loss of the photoactvity.

Original languageEnglish
Article number11933
JournalScientific Reports
Volume5
DOIs
Publication statusPublished - 2015 Jul 7

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nanowires
nanoparticles
oxygen
photocurrents
synchrotrons
x ray diffraction
electron microscopes
illumination
nucleation
oxidation
electrodes
augmentation
high resolution
gases
water

ASJC Scopus subject areas

  • General

Cite this

Structural Evolution of Chemically-Driven RuO<inf>2</inf> Nanowires and 3-Dimensional Design for Photo-Catalytic Applications. / Park, Joonmo; Lee, Jae Won; Ye, Byeong Uk; Chun, Sung He; Joo, Sang Hoon; Park, Hyunwoong; Lee, Heon; Jeong, Hu Young; Kim, Myung Hwa; Baik, Jeong Min.

In: Scientific Reports, Vol. 5, 11933, 07.07.2015.

Research output: Contribution to journalArticle

Park, Joonmo ; Lee, Jae Won ; Ye, Byeong Uk ; Chun, Sung He ; Joo, Sang Hoon ; Park, Hyunwoong ; Lee, Heon ; Jeong, Hu Young ; Kim, Myung Hwa ; Baik, Jeong Min. / Structural Evolution of Chemically-Driven RuO<inf>2</inf> Nanowires and 3-Dimensional Design for Photo-Catalytic Applications. In: Scientific Reports. 2015 ; Vol. 5.
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abstract = "Growth mechanism of chemically-driven RuO2 nanowires is explored and used to fabricate three-dimensional RuO2 branched Au-TiO2 nanowire electrodes for the photostable solar water oxidation. For the real time structural evolution during the nanowire growth, the amorphous RuO2 precursors (Ru(OH)3·H2O) are heated at 180 °C, producing the RuO2 nanoparticles with the tetragonal crystallographic structure and Ru enriched amorphous phases, observed through the in-situ synchrotron x-ray diffraction and the high-resolution transmission electron microscope images. Growth then proceeds by Ru diffusion to the nanoparticles, followed by the diffusion to the growing surface of the nanowire in oxygen ambient, supported by the nucleation theory. The RuO2 branched Au-TiO2 nanowire arrays shows a remarkable enhancement in the photocurrent density by approximately 60{\%} and 200{\%}, in the UV-visible and Visible region, respectively, compared with pristine TiO2 nanowires. Furthermore, there is no significant decrease in the device's photoconductance with UV-visible illumination during 1 day, making it possible to produce oxygen gas without the loss of the photoactvity.",
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