Structure and unusual substitution reaction of oligoether-appended β-diketonato strontium complex

Yo S. Min, Young Jin Cho, Jung Hyun Lee, Daesig Kim, Il Yoon, Ki M. Park, Shim Sung Lee, Bong-Rae Cho

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The structure of an oligoether-appended β-diketonato strontium complex in both solution and solid state was studied. It was reported that the complex exists as [SrL2]2 (1) [L= 1-(2-methoxyethoxy)-2,2,6,6-tetramethyl-3,5-heptanedionate] in solution and liquid state. The structure of 1 in CDCl3 was examined by nuclear magnetic resonance (NMR) spectroscopy. It was shown that both 1H and 13CNMR spectra of 1 were indistinguishable from what would be expected from a 1:1 complex between the strontium ion and the ligand. A crystal sample was obtained by standing a solution of 1 in methanol/water, co-solvent at -5°C.

Original languageEnglish
Pages (from-to)241-244
Number of pages4
JournalChemical Vapor Deposition
Volume9
Issue number5
DOIs
Publication statusPublished - 2003 Oct 1

Fingerprint

Strontium
strontium
Substitution reactions
substitutes
magnetic resonance spectroscopy
Nuclear magnetic resonance spectroscopy
Methanol
methyl alcohol
Ligands
Ions
solid state
nuclear magnetic resonance
Crystals
ligands
Water
Liquids
liquids
water
crystals
ions

ASJC Scopus subject areas

  • Process Chemistry and Technology
  • Electrochemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Condensed Matter Physics
  • Surfaces and Interfaces

Cite this

Structure and unusual substitution reaction of oligoether-appended β-diketonato strontium complex. / Min, Yo S.; Cho, Young Jin; Lee, Jung Hyun; Kim, Daesig; Yoon, Il; Park, Ki M.; Lee, Shim Sung; Cho, Bong-Rae.

In: Chemical Vapor Deposition, Vol. 9, No. 5, 01.10.2003, p. 241-244.

Research output: Contribution to journalArticle

Min, Yo S. ; Cho, Young Jin ; Lee, Jung Hyun ; Kim, Daesig ; Yoon, Il ; Park, Ki M. ; Lee, Shim Sung ; Cho, Bong-Rae. / Structure and unusual substitution reaction of oligoether-appended β-diketonato strontium complex. In: Chemical Vapor Deposition. 2003 ; Vol. 9, No. 5. pp. 241-244.
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