Study on characteristics of phosphates and transition-metal complexes synthesized onto viscose rayon felt for flame retardancy

Jeong Su Kim, Ung Su Choi, Young Gun Ko, Sung Hyun Kim

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Phosphates (polyphosphate and ammonium phosphate) are synthesized onto the viscose rayon felt as high-performance materials for flame retardancy. This surface reaction has advantages of non-blooming effect and application to thermosetting plastics. Metal complexes have been known to have the effect of reducing amounts of smoke. Therefore, in second step, transition metal complexes were synthesized onto the viscose rayon ammonium phosphate felt. This article focuses on surface modification of phosphates and metal complex onto viscose rayon. All reactions were confirmed by ATR FT-IR and TOF-SIMS. As concentrations of phosphoric acid and urea increased, peak intensities of ammonium ion group and phosphate groups grew up highly. The thermal properties of the synthesized materials were studied using thermal gravimetric analysis (TGA) and oxygen index test. On the basis of experimental results, the synthesized materials for flame retardancy showed excellent physico-chemical and thermal effect, and found to be as the flame retardants.

Original languageEnglish
Pages (from-to)218-224
Number of pages7
JournalJournal of Industrial and Engineering Chemistry
Volume8
Issue number3
Publication statusPublished - 2002 Dec 1

Fingerprint

Rayon
Coordination Complexes
Metal complexes
Transition metals
Phosphates
Flame Retardants
Polyphosphates
Gravimetric analysis
Surface reactions
Secondary ion mass spectrometry
Ammonium Compounds
Smoke
Thermal effects
Surface treatment
Urea
Thermodynamic properties
Ions
Oxygen
Plastics
Phosphoric acid

Keywords

  • Flame retardants
  • Metal complex
  • Phosphate
  • Surface reaction
  • Viscose rayon

ASJC Scopus subject areas

  • Engineering (miscellaneous)

Cite this

Study on characteristics of phosphates and transition-metal complexes synthesized onto viscose rayon felt for flame retardancy. / Kim, Jeong Su; Choi, Ung Su; Ko, Young Gun; Kim, Sung Hyun.

In: Journal of Industrial and Engineering Chemistry, Vol. 8, No. 3, 01.12.2002, p. 218-224.

Research output: Contribution to journalArticle

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