Sulfonation of PIM-1 - Towards highly oxygen permeable binders for fuel cell application

Byoung Gak Kim, Dirk Henkensmeier, Hyoung Juhn Kim, Jong Hyun Jang, SukWoo Nam, Tae Hoon Lim

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The development of alternative, non-fluorinated membranes for polymer electrolyte membrane fuel cells necessitates the co-development of a non-fluorinated electrode catalyst binder to ensure compatibility between membrane and electrode. However, most hydrocarbon based polymers have lower gas permeability than perfluorinated Nafion. In this work we tried to obtain a sulfonated, non-fluorinated binder based on PIM-1 (polymer of intrinsic microporosity 1) which has up to 2000 times higher permeability than Nafion. However, sulfonation was not straightforward and often led to degradative side reactions. Sulfonated polymers were too brittle to give stable membranes and the highest experimental IEC was 1.03 meq/g, significantly lower than the theoretical IEC of 3.2 meq/g (2 sulfonic acid groups per repeat unit). [Figure not available: see fulltext.]

Original languageEnglish
Pages (from-to)92-98
Number of pages7
JournalMacromolecular Research
Volume22
Issue number1
DOIs
Publication statusPublished - 2014 Jan 1
Externally publishedYes

Fingerprint

Sulfonation
Microporosity
Binders
Fuel cells
Polymers
Oxygen
Membranes
Electrodes
Gas permeability
Sulfonic Acids
Proton exchange membrane fuel cells (PEMFC)
Hydrocarbons
Catalysts
Acids
perfluorosulfonic acid

Keywords

  • electrode binder
  • PIM
  • polymer electrolyte fuel cell (PEFC)
  • polymer of intrinsic microporosity
  • sulfonation

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Chemical Engineering(all)

Cite this

Kim, B. G., Henkensmeier, D., Kim, H. J., Jang, J. H., Nam, S., & Lim, T. H. (2014). Sulfonation of PIM-1 - Towards highly oxygen permeable binders for fuel cell application. Macromolecular Research, 22(1), 92-98. https://doi.org/10.1007/s13233-014-2007-z

Sulfonation of PIM-1 - Towards highly oxygen permeable binders for fuel cell application. / Kim, Byoung Gak; Henkensmeier, Dirk; Kim, Hyoung Juhn; Jang, Jong Hyun; Nam, SukWoo; Lim, Tae Hoon.

In: Macromolecular Research, Vol. 22, No. 1, 01.01.2014, p. 92-98.

Research output: Contribution to journalArticle

Kim, Byoung Gak ; Henkensmeier, Dirk ; Kim, Hyoung Juhn ; Jang, Jong Hyun ; Nam, SukWoo ; Lim, Tae Hoon. / Sulfonation of PIM-1 - Towards highly oxygen permeable binders for fuel cell application. In: Macromolecular Research. 2014 ; Vol. 22, No. 1. pp. 92-98.
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