Supersonic nanoblowing: A new ultra-stiff phase of nylon 6 in 20-50 nm confinement

Suman Sinha-Ray, Min Wook Lee, Sumit Sinha-Ray, Seongpil An, Behnam Pourdeyhimi, Sam S. Yoon, Alexander L. Yarin

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

The 20-50 nm nanofibers hold great promise as functional fabrics, biomedical materials, filters, fuel cell membranes, ultra-speed fiber optics, electronics and sensorics. In our novel process of supersonic solution blowing of nylon-6, 20-50 nm nanofibers are obtained. Here we found a new phase of nylon-6, which differs from the known α-, β-, γ-, δ- and λ-phases, presenting itself as a novel χ-phase. It is characterized by the decrease of CH2 stretching, a shift of -NH stretching, a different type of hydrogen bond and a ten-fold increase in Young's modulus compared to those of post-processed macroscopic nylon fibers.

Original languageEnglish
Pages (from-to)3491-3498
Number of pages8
JournalJournal of Materials Chemistry C
Volume1
Issue number21
DOIs
Publication statusPublished - 2013 Jun 7

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

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    Sinha-Ray, S., Lee, M. W., Sinha-Ray, S., An, S., Pourdeyhimi, B., Yoon, S. S., & Yarin, A. L. (2013). Supersonic nanoblowing: A new ultra-stiff phase of nylon 6 in 20-50 nm confinement. Journal of Materials Chemistry C, 1(21), 3491-3498. https://doi.org/10.1039/c3tc30248b