Surface modification of a six-capped body-centered cube Ni 9W6 cluster: Structure and single-molecule magnetism

Jeong Hak Lim, Jung Hee Yoon, Hyoung Chan Kim, Chang Seop Hong

Research output: Contribution to journalArticle

131 Citations (Scopus)

Abstract

To cap it off: A high-spin cyanide-bridged Ni9W6 cluster (S = 12) shows ferromagnetic coupling between NiII (green) and WV (purple) ions within the molecule. The surface was modified by substituting the solvent molecules on the surface of the cluster with 2,2′-bipyridine to afford an air-stable Ni9W6 cluster with single-molecule magnetism. (Figure Presented).

Original languageEnglish
Pages (from-to)7424-7426
Number of pages3
JournalAngewandte Chemie - International Edition
Volume45
Issue number44
DOIs
Publication statusPublished - 2006 Nov 13

Keywords

  • Cluster compounds
  • Cyanides
  • Magnetic properties
  • Nickel
  • Single-molecule studies

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Fingerprint Dive into the research topics of 'Surface modification of a six-capped body-centered cube Ni <sub>9</sub>W<sub>6</sub> cluster: Structure and single-molecule magnetism'. Together they form a unique fingerprint.

  • Cite this