Swelling and shrinkage of lamellar domain of conformationally restricted block copolymers by metal chloride

Dong Hyun Lee, Hwang Yong Kim, Jin Kon Kim, June Huh, Du Yeol Ryu

Research output: Contribution to journalArticle

58 Citations (Scopus)

Abstract

The phenomena of swelling and shrinkage of lamellar domain of conformationally restricted block copolymers by metal chloride, was studied. The addition of additives such as homopolymer to a block copolymer provided a relatively simple means to control the period. The periodicity of block copolymer mesophase was achieved by introducing the coordination between metal halide and a functional group. The block copolymers were found to show a rich variety of spatially periodic nanostructures due to their ability of molecular self-assembly.

Original languageEnglish
Pages (from-to)2027-2030
Number of pages4
JournalMacromolecules
Volume39
Issue number6
DOIs
Publication statusPublished - 2006 Mar 21
Externally publishedYes

Fingerprint

Block copolymers
Swelling
Chlorides
Metals
Metal halides
Homopolymerization
Self assembly
Functional groups
Nanostructures

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Swelling and shrinkage of lamellar domain of conformationally restricted block copolymers by metal chloride. / Lee, Dong Hyun; Kim, Hwang Yong; Kim, Jin Kon; Huh, June; Ryu, Du Yeol.

In: Macromolecules, Vol. 39, No. 6, 21.03.2006, p. 2027-2030.

Research output: Contribution to journalArticle

Lee, Dong Hyun ; Kim, Hwang Yong ; Kim, Jin Kon ; Huh, June ; Ryu, Du Yeol. / Swelling and shrinkage of lamellar domain of conformationally restricted block copolymers by metal chloride. In: Macromolecules. 2006 ; Vol. 39, No. 6. pp. 2027-2030.
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