Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts

Ming Yu Jin; Sun Min Kim; Hogyu Han; Do Hyun Ryu; Jung Woon Yang

doi:10.1021/ol102937w

Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts

Ming Yu Jin, Sun Min Kim, Hogyu Han, Do Hyun Ryu, Jung Woon Yang

College of Science

Research output: Contribution to journal › Article › peer-review

74 Citations (Scopus)

Abstract

An unprecedented high level of regioselectivities (up to 96%) in the intermolecular crossed acyloin condensations of various aromatic aldehydes with acetaldehyde was realized by an appropriate choice of N-heterocyclic carbene catalysts.(Figure Presented)

Original language	English
Pages (from-to)	880-883
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	5
DOIs	https://doi.org/10.1021/ol102937w
Publication status	Published - 2011 Mar 4

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol102937w

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@article{7f76a3adf4a44ddd82b0a876ba425992,

title = "Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts",

abstract = "An unprecedented high level of regioselectivities (up to 96%) in the intermolecular crossed acyloin condensations of various aromatic aldehydes with acetaldehyde was realized by an appropriate choice of N-heterocyclic carbene catalysts.(Figure Presented)",

author = "Jin, {Ming Yu} and Kim, {Sun Min} and Hogyu Han and Ryu, {Do Hyun} and Yang, {Jung Woon}",

year = "2011",

month = mar,

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doi = "10.1021/ol102937w",

language = "English",

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pages = "880--883",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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T1 - Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts

AU - Jin, Ming Yu

AU - Kim, Sun Min

AU - Han, Hogyu

AU - Ryu, Do Hyun

AU - Yang, Jung Woon

PY - 2011/3/4

Y1 - 2011/3/4

N2 - An unprecedented high level of regioselectivities (up to 96%) in the intermolecular crossed acyloin condensations of various aromatic aldehydes with acetaldehyde was realized by an appropriate choice of N-heterocyclic carbene catalysts.(Figure Presented)

AB - An unprecedented high level of regioselectivities (up to 96%) in the intermolecular crossed acyloin condensations of various aromatic aldehydes with acetaldehyde was realized by an appropriate choice of N-heterocyclic carbene catalysts.(Figure Presented)

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U2 - 10.1021/ol102937w

DO - 10.1021/ol102937w

M3 - Article

C2 - 21280664

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SN - 1523-7060

VL - 13

SP - 880

EP - 883

JO - Organic Letters

JF - Organic Letters

IS - 5

ER -

Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts

Abstract

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