Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts

Ming Yu Jin, Sun Min Kim, Hogyu Han, Do Hyun Ryu, Jung Woon Yang

Research output: Contribution to journalArticle

61 Citations (Scopus)

Abstract

An unprecedented high level of regioselectivities (up to 96%) in the intermolecular crossed acyloin condensations of various aromatic aldehydes with acetaldehyde was realized by an appropriate choice of N-heterocyclic carbene catalysts.(Figure Presented)

Original languageEnglish
Pages (from-to)880-883
Number of pages4
JournalOrganic Letters
Volume13
Issue number5
DOIs
Publication statusPublished - 2011 Mar 4

Fingerprint

Regioselectivity
Acetaldehyde
acetaldehyde
carbenes
aldehydes
Aldehydes
Condensation
condensation
catalysts
Catalysts
carbene
acyloin

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Biochemistry

Cite this

Switching regioselectivity in crossed acyloin condensations between aromatic aldehydes and acetaldehyde by altering n -heterocyclic carbene catalysts. / Jin, Ming Yu; Kim, Sun Min; Han, Hogyu; Ryu, Do Hyun; Yang, Jung Woon.

In: Organic Letters, Vol. 13, No. 5, 04.03.2011, p. 880-883.

Research output: Contribution to journalArticle

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