Synthesis and characterization of functionalized sol-gel materials for electro-optical application

Dong Hoon Choi, Jong Soo Ahn, Sun Jin Lim, Sangyup Song, Woong Sang Jahng, Nakjoong Kim

Research output: Contribution to journalArticle

Abstract

We simply synthesized the triethoxysilane bearing the second-order nonlinear optical(NLO) active chromophore in the side chain. In order to improve the poor temporal stability of second-order NLO effect, we introduced the thermal crosslink between the side chain themselves. We prepared two different silane solutions; one is composed of triethoxysilane with NLO chromophore (SGDR1) only. The other consists of SGDR1 and 3-glycidoxypropyl trimethoxysitane. Thermal crosslink formation was traced with in-situ infrared spectroscopy. We achieved much improvement of the temporal stability of second-order NLO effect utilizing this crosslinked composite system.

Original languageEnglish
Pages (from-to)11-14
Number of pages4
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume294-95
Issue number0
Publication statusPublished - 1997 Dec 1
Externally publishedYes

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Chromophores
chromophores
Sol-gels
Bearings (structural)
gels
Silanes
synthesis
silanes
Large scale systems
Infrared spectroscopy
infrared spectroscopy
composite materials
Hot Temperature
triethoxysilane

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

Synthesis and characterization of functionalized sol-gel materials for electro-optical application. / Choi, Dong Hoon; Ahn, Jong Soo; Lim, Sun Jin; Song, Sangyup; Jahng, Woong Sang; Kim, Nakjoong.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 294-95, No. 0, 01.12.1997, p. 11-14.

Research output: Contribution to journalArticle

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