Synthesis and electrochemical properties of Li3V 2(PO4)3-LiMnPO4 composite cathode material for lithium-ion batteries

Jin Shik Yun, Soo Kim, Byung Won Cho, Kwan Young Lee, Kyung Yoon Chung, Wonyoung Chang

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Carbon-coated Li3V2(PO4) 3-LiMnPO4 composite cathode materials are first reported in this work, prepared by the mechanochemical process with a complex metal oxide as the precursor and sucrose as the carbon source. X-ray diffraction pattern of the composite material indicates that both olivine LiMnPO4 and monoclinic Li3V2(PO4)3 co-exist. We further investigated the electrochemical properties of our Li3V 2(PO4)3-LiMnPO4 composite cathode materials using galvanostatic charging/discharging tests, where our Li 3V2(PO4)3-LiMnPO4 composite electrode materials exhibit the charge/discharge efficiency of 91.9%, while Li3V2(PO4)3 and LiMnPO 4 exhibit the efficiency of 87.7 and 86.7% in the first cycle. The composites display unique electrochemical performances in terms of overvoltage and cycle stability, displaying a reduced gap of 141.6 mV between charge and discharge voltage and 95.0% capacity efficiency after 15th cycles.

Original languageEnglish
Pages (from-to)433-436
Number of pages4
JournalBulletin of the Korean Chemical Society
Volume34
Issue number2
DOIs
Publication statusPublished - 2013 Feb 20

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Electrochemical properties
Cathodes
Composite materials
Carbon
Coordination Complexes
Oxides
Diffraction patterns
Sucrose
Lithium-ion batteries
X ray diffraction
Electrodes
Electric potential

Keywords

  • Composite
  • Li-ion batteries
  • LiV (PO)
  • LiMnPO
  • Mechanochemical process

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis and electrochemical properties of Li3V 2(PO4)3-LiMnPO4 composite cathode material for lithium-ion batteries. / Yun, Jin Shik; Kim, Soo; Cho, Byung Won; Lee, Kwan Young; Chung, Kyung Yoon; Chang, Wonyoung.

In: Bulletin of the Korean Chemical Society, Vol. 34, No. 2, 20.02.2013, p. 433-436.

Research output: Contribution to journalArticle

Yun, Jin Shik ; Kim, Soo ; Cho, Byung Won ; Lee, Kwan Young ; Chung, Kyung Yoon ; Chang, Wonyoung. / Synthesis and electrochemical properties of Li3V 2(PO4)3-LiMnPO4 composite cathode material for lithium-ion batteries. In: Bulletin of the Korean Chemical Society. 2013 ; Vol. 34, No. 2. pp. 433-436.
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AU - Chang, Wonyoung

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AB - Carbon-coated Li3V2(PO4) 3-LiMnPO4 composite cathode materials are first reported in this work, prepared by the mechanochemical process with a complex metal oxide as the precursor and sucrose as the carbon source. X-ray diffraction pattern of the composite material indicates that both olivine LiMnPO4 and monoclinic Li3V2(PO4)3 co-exist. We further investigated the electrochemical properties of our Li3V 2(PO4)3-LiMnPO4 composite cathode materials using galvanostatic charging/discharging tests, where our Li 3V2(PO4)3-LiMnPO4 composite electrode materials exhibit the charge/discharge efficiency of 91.9%, while Li3V2(PO4)3 and LiMnPO 4 exhibit the efficiency of 87.7 and 86.7% in the first cycle. The composites display unique electrochemical performances in terms of overvoltage and cycle stability, displaying a reduced gap of 141.6 mV between charge and discharge voltage and 95.0% capacity efficiency after 15th cycles.

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