Synthesis and Li electroactivity of Fe 2P 2O 7 microspheres composed of self-assembled nanorods

Gwang Hee Lee, Seung Deok Seo, Hyun Woo Shim, Kyung Soo Park, Dong-Wan Kim

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Iron phosphate (Fe(II) 2P 20 7) microspheres composed of self-assembled nanorods were prepared by means of thermal dehydrogenation followed by thermochemical reduction of hydrothermally- synthesized FePO 4·2H 20 at 400°C under a H 2 atmosphere. The phase and morphological evolutions of FePO 4·2H 20 and Fe 2P 2O 7 products were characterized by X-ray diffraction. The Fe 2P 2O 7 electrode as a new anode showed higher specific capacities (490 mA h g -1 after 10 cycles at a rate of 100 mA g -1) and better cyclic performances than FePO 4· 2H 20.

Original languageEnglish
Pages (from-to)6927-6930
Number of pages4
JournalCeramics International
Volume38
Issue number8
DOIs
Publication statusPublished - 2012 Dec 1
Externally publishedYes

Fingerprint

Dehydrogenation
Nanorods
Microspheres
Anodes
Phosphates
Iron
X ray diffraction
Electrodes
Hot Temperature

Keywords

  • E. Li-ion battery electrodes
  • Fe P O
  • Microspheres
  • Thermochemical reduction

ASJC Scopus subject areas

  • Ceramics and Composites
  • Process Chemistry and Technology
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Synthesis and Li electroactivity of Fe 2P 2O 7 microspheres composed of self-assembled nanorods. / Lee, Gwang Hee; Seo, Seung Deok; Shim, Hyun Woo; Park, Kyung Soo; Kim, Dong-Wan.

In: Ceramics International, Vol. 38, No. 8, 01.12.2012, p. 6927-6930.

Research output: Contribution to journalArticle

Lee, Gwang Hee ; Seo, Seung Deok ; Shim, Hyun Woo ; Park, Kyung Soo ; Kim, Dong-Wan. / Synthesis and Li electroactivity of Fe 2P 2O 7 microspheres composed of self-assembled nanorods. In: Ceramics International. 2012 ; Vol. 38, No. 8. pp. 6927-6930.
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