Synthesis and properties of high MW Poly(D,L-lactic acid)s by direct thermal condensation

Gwi Im Shin, Ji Heung Kim, Soo Hyun Kim, Young Ha Kim

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Poly (L-lactic acid), (PLLA) and its D,L-copolymers have been prepared by direct polycondensation method and their thermal and mechanical properties were examined. A multifunctional alcohol, dipentaerythritol, was introduced as a branching monomer in the preparation of PLLA and D,L-copolymers with star-shaped macromolecular structure to overcome the molecular weight limitation problems in the direct condensation of lactic acid. High molecular weight polymers with inherent viscosity values within the range of 0.7∼1.0 dL/g (Mn of about 30,000-40,000 daltons by GPC) were prepared and cast into the transparent, flexible films. Thermal analysis showed that the glass transition temperatures of the polymers were within the range of 45-55 °C. The melting temperature and degree of crystallinity decreased as the number of D-lactic acid unit in the copolymer increased. These star-shaped PLLA and D,L-copolymers had a slightly lower decomposition temperature than that of the linear poly (lactic acid), implying that the branched one has less thermal stability. It was found, however, that they showed good mechanical properties, and that the brittle nature of PLLA could be quite improved in D,L-copolymers as proved by the tensile strength measurements.

Original languageEnglish
Pages (from-to)19-25
Number of pages7
JournalKorea Polymer Journal
Volume5
Issue number1
Publication statusPublished - 1997 Dec 1
Externally publishedYes

Fingerprint

Lactic acid
Condensation
Lactic Acid
Copolymers
Stars
Polymers
Molecular weight
Mechanical properties
Polycondensation
Thermoanalysis
Melting point
Thermodynamic stability
Tensile strength
Thermodynamic properties
Monomers
Alcohols
Hot Temperature
poly(lactic acid)
Viscosity
Decomposition

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Polymers and Plastics

Cite this

Shin, G. I., Kim, J. H., Kim, S. H., & Kim, Y. H. (1997). Synthesis and properties of high MW Poly(D,L-lactic acid)s by direct thermal condensation. Korea Polymer Journal, 5(1), 19-25.

Synthesis and properties of high MW Poly(D,L-lactic acid)s by direct thermal condensation. / Shin, Gwi Im; Kim, Ji Heung; Kim, Soo Hyun; Kim, Young Ha.

In: Korea Polymer Journal, Vol. 5, No. 1, 01.12.1997, p. 19-25.

Research output: Contribution to journalArticle

Shin, GI, Kim, JH, Kim, SH & Kim, YH 1997, 'Synthesis and properties of high MW Poly(D,L-lactic acid)s by direct thermal condensation', Korea Polymer Journal, vol. 5, no. 1, pp. 19-25.
Shin, Gwi Im ; Kim, Ji Heung ; Kim, Soo Hyun ; Kim, Young Ha. / Synthesis and properties of high MW Poly(D,L-lactic acid)s by direct thermal condensation. In: Korea Polymer Journal. 1997 ; Vol. 5, No. 1. pp. 19-25.
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