Synthesis and properties of soluble organic p-type semiconductor based on TIPS-anthracene moiety

Ki Hwa Jung; Kyung Hwan Kim; Tae Wan Lee; Min Ju Cho; Mi Yeon Cho; Ji Won Shin; Jin Soo Joo; Dong Hoon Choi

doi:10.1080/15421400902938993

Synthesis and properties of soluble organic p-type semiconductor based on TIPS-anthracene moiety

Ki Hwa Jung, Kyung Hwan Kim, Tae Wan Lee, Min Ju Cho, Mi Yeon Cho, Ji Won Shin, Jin Soo Joo, Dong Hoon Choi

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

New multi-branched molecules have been synthesized through Horner-Emmons reactions using 10-((triisopropylsilyl)ethynyl) anthracene-9-carbaldehyde as dendrons and octaethyl benzene-1,2,4,5-tetrayltetrakis(methylene) tetraphosphonate as a reactive core unit; these molecules have been fully characterized. Two anthracene-based star-shaped molecules exhibit good solubility in common organic solvents and good self-film forming properties. The four-armed molecule, 4(TIPS-ant)-benzene is intrinsically crystalline as they exhibit well-defined X-ray diffraction patterns from relatively uniform orientations of molecules. According to the AFM analysis, 4(TIPS-ant)-benzene helps in attaining good network interconnection of the carrier transport channel, which is responsible for the charge carrier mobility in solution-processed organic semiconductors for organic thin film transistor (OTFT).

Original language	English
Pages (from-to)	18-26
Number of pages	9
Journal	Molecular Crystals and Liquid Crystals
Volume	504
Issue number	1
DOIs	https://doi.org/10.1080/15421400902938993
Publication status	Published - 2009 Jan 1

Keywords

Multi-branched molecule
Organic thin filmtransistor
Soluble semiconductor

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1080/15421400902938993

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title = "Synthesis and properties of soluble organic p-type semiconductor based on TIPS-anthracene moiety",

abstract = "New multi-branched molecules have been synthesized through Horner-Emmons reactions using 10-((triisopropylsilyl)ethynyl) anthracene-9-carbaldehyde as dendrons and octaethyl benzene-1,2,4,5-tetrayltetrakis(methylene) tetraphosphonate as a reactive core unit; these molecules have been fully characterized. Two anthracene-based star-shaped molecules exhibit good solubility in common organic solvents and good self-film forming properties. The four-armed molecule, 4(TIPS-ant)-benzene is intrinsically crystalline as they exhibit well-defined X-ray diffraction patterns from relatively uniform orientations of molecules. According to the AFM analysis, 4(TIPS-ant)-benzene helps in attaining good network interconnection of the carrier transport channel, which is responsible for the charge carrier mobility in solution-processed organic semiconductors for organic thin film transistor (OTFT).",

keywords = "Multi-branched molecule, Organic thin filmtransistor, Soluble semiconductor",

author = "Jung, {Ki Hwa} and Kim, {Kyung Hwan} and Lee, {Tae Wan} and Cho, {Min Ju} and Cho, {Mi Yeon} and Shin, {Ji Won} and Joo, {Jin Soo} and Choi, {Dong Hoon}",

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AU - Jung, Ki Hwa

AU - Kim, Kyung Hwan

AU - Lee, Tae Wan

AU - Cho, Min Ju

AU - Cho, Mi Yeon

AU - Shin, Ji Won

AU - Joo, Jin Soo

AU - Choi, Dong Hoon

PY - 2009/1/1

Y1 - 2009/1/1

N2 - New multi-branched molecules have been synthesized through Horner-Emmons reactions using 10-((triisopropylsilyl)ethynyl) anthracene-9-carbaldehyde as dendrons and octaethyl benzene-1,2,4,5-tetrayltetrakis(methylene) tetraphosphonate as a reactive core unit; these molecules have been fully characterized. Two anthracene-based star-shaped molecules exhibit good solubility in common organic solvents and good self-film forming properties. The four-armed molecule, 4(TIPS-ant)-benzene is intrinsically crystalline as they exhibit well-defined X-ray diffraction patterns from relatively uniform orientations of molecules. According to the AFM analysis, 4(TIPS-ant)-benzene helps in attaining good network interconnection of the carrier transport channel, which is responsible for the charge carrier mobility in solution-processed organic semiconductors for organic thin film transistor (OTFT).

AB - New multi-branched molecules have been synthesized through Horner-Emmons reactions using 10-((triisopropylsilyl)ethynyl) anthracene-9-carbaldehyde as dendrons and octaethyl benzene-1,2,4,5-tetrayltetrakis(methylene) tetraphosphonate as a reactive core unit; these molecules have been fully characterized. Two anthracene-based star-shaped molecules exhibit good solubility in common organic solvents and good self-film forming properties. The four-armed molecule, 4(TIPS-ant)-benzene is intrinsically crystalline as they exhibit well-defined X-ray diffraction patterns from relatively uniform orientations of molecules. According to the AFM analysis, 4(TIPS-ant)-benzene helps in attaining good network interconnection of the carrier transport channel, which is responsible for the charge carrier mobility in solution-processed organic semiconductors for organic thin film transistor (OTFT).

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Synthesis and properties of soluble organic p-type semiconductor based on TIPS-anthracene moiety

Abstract

Keywords

ASJC Scopus subject areas

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