Synthesis of Mg₂FeH₆ by hydrogenation of Mg/Fe powder mixture prepared by cold roll milling in air: Effects of microstructure and oxygen distribution

Herein, we describe the synthesis of Mg₂FeH₆ by hydrogenation of a 2.1 Mg:Fe (mol/mol) powder mixture prepared by cold roll milling (CRM) in air. The thickness of Fe layers and the amount and distribution of oxygen with number of CRM passes were systematically analyzed. CRM-induced microstructural changes were shown to play an important role in Mg₂FeH₆ formation. Although repeated CRM effectively decreased the Fe layer thickness to values sufficient for the fast formation of Mg₂FeH₆, too much CRM passes decreased the total degree of hydrogenation due to inevitable oxidation of Mg in air. Both microstructure refinement and minimal oxidation are the prerequisites for efficient Mg₂FeH₆ synthesis, with the former condition being achievable by optimizing the number of milling passes, and the latter one requiring CRM under an inert atmosphere.