Synthesis of uniform silica particles with controlled size by organic amine base catalysts via one-step process

Jin Han, Taekyung Yu, Sang Hyuk Im

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Uniform silica particles were synthesized by synergistic combination of sodium 4-styrene sulfonate (NaSS) anionic surfactant and organic amine base catalyst such as ethylenediamine (EDA) or diethylenetriamine (DETA). The EDA and DETA organic amine base catalysts could promote the growth reaction rate so that they produced larger silica particles compared to the NH4OH base catalyst because the organic amines provide more basic micro-environment near the surface of the silica particle due to multiple amine groups in a single molecule. Accordingly, the size of the silica particle was 450 ± 12 nm (NH4OH), 725 ± 21 nm (EDA), and 942 ± 130 nm (DETA) in similar pH conditions.

Original languageEnglish
Pages (from-to)376-381
Number of pages6
JournalJournal of Industrial and Engineering Chemistry
Volume52
DOIs
Publication statusPublished - 2017 Aug 25

Fingerprint

ethylenediamine
Silicon Dioxide
Amines
Silica
Catalysts
Styrene
Anionic surfactants
Reaction rates
Sodium
Molecules
diethylenetriamine

Keywords

  • Anionic surfactant
  • Diethylenetriamine
  • Ethylenediamine
  • Organic amine
  • Silica particles

ASJC Scopus subject areas

  • Chemical Engineering(all)

Cite this

Synthesis of uniform silica particles with controlled size by organic amine base catalysts via one-step process. / Han, Jin; Yu, Taekyung; Im, Sang Hyuk.

In: Journal of Industrial and Engineering Chemistry, Vol. 52, 25.08.2017, p. 376-381.

Research output: Contribution to journalArticle

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