Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane

Sung Kwan Kim, Tae Jin Kim, Tae Young Kim, Gaehang Lee, Joon T. Park, SukWoo Nam, Sang Ook Kang

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

Palladium nanoparticles (PdNPs) were conveniently prepared in tetraglyme (TG) solution using a variety of palladium precursors. At 140°C, TG promoted Pd 3(OAc) 6 to produce irregular shaped PdNPs with an average size of 4 nm. When these PdNPs were re-dispersed in TG and used for the dehydrogenation of ammonia borane (AB) at 85°C, remarkably enhanced catalytic performance was achieved to release 2.3 equiv. of H 2 in 1 h.

Original languageEnglish
Pages (from-to)2021-2023
Number of pages3
JournalChemical Communications
Volume48
Issue number14
DOIs
Publication statusPublished - 2012 Feb 14
Externally publishedYes

Fingerprint

Boranes
Palladium
Dehydrogenation
Ammonia
Nanoparticles
tetraglyme

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Kim, S. K., Kim, T. J., Kim, T. Y., Lee, G., Park, J. T., Nam, S., & Kang, S. O. (2012). Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane. Chemical Communications, 48(14), 2021-2023. https://doi.org/10.1039/c2cc15931g

Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane. / Kim, Sung Kwan; Kim, Tae Jin; Kim, Tae Young; Lee, Gaehang; Park, Joon T.; Nam, SukWoo; Kang, Sang Ook.

In: Chemical Communications, Vol. 48, No. 14, 14.02.2012, p. 2021-2023.

Research output: Contribution to journalArticle

Kim, SK, Kim, TJ, Kim, TY, Lee, G, Park, JT, Nam, S & Kang, SO 2012, 'Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane', Chemical Communications, vol. 48, no. 14, pp. 2021-2023. https://doi.org/10.1039/c2cc15931g
Kim, Sung Kwan ; Kim, Tae Jin ; Kim, Tae Young ; Lee, Gaehang ; Park, Joon T. ; Nam, SukWoo ; Kang, Sang Ook. / Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane. In: Chemical Communications. 2012 ; Vol. 48, No. 14. pp. 2021-2023.
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