Tetragonal distortion and the domain structure of thin Pb(Zr,Ti)O3/MgO(100) films

D. Y. Noh, H. C. Kang, Tae Yeon Seong, J. H. Je, H. K. Kim

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The paraelectric-cubic to ferroelectric-tetragonal phase transformation of thin Pb(Zr,Ti)O3/MgO(100) films was studied in synchrotron X-ray scattering experiments. In the thin epitaxial films, the tetragonal distortion of the ferroelectric phase and the transition temperature were significantly reduced. In sharp contrast to the reported mixture of the a-type and the c-type domains in thicker films, the 250-Å-thick film was purely composed of the c-type domains in the tetragonal phase. We attribute the suppression of the transition to the substrate effect, which prefers the c-type domains near the interface, and reduces the tetragonal distortion to minimize the strain energy caused by the lattice mismatch.

Original languageEnglish
Pages (from-to)343-346
Number of pages4
JournalApplied Physics A: Materials Science and Processing
Volume67
Issue number3
Publication statusPublished - 1998 Dec 1
Externally publishedYes

Fingerprint

Thick films
Ferroelectric materials
Lattice mismatch
thick films
Epitaxial films
Strain energy
X ray scattering
Synchrotrons
Superconducting transition temperature
Phase transitions
Thin films
phase transformations
synchrotrons
Substrates
transition temperature
retarding
Experiments
thin films
scattering
x rays

ASJC Scopus subject areas

  • Materials Science(all)
  • Physics and Astronomy (miscellaneous)

Cite this

Tetragonal distortion and the domain structure of thin Pb(Zr,Ti)O3/MgO(100) films. / Noh, D. Y.; Kang, H. C.; Seong, Tae Yeon; Je, J. H.; Kim, H. K.

In: Applied Physics A: Materials Science and Processing, Vol. 67, No. 3, 01.12.1998, p. 343-346.

Research output: Contribution to journalArticle

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