The effect of manganese oxide precursors on the characteristics of LiMn2O4 cathode particles

Seo Hee Ju, Hee Chan Jang, Man Jong Lee, Yun Chan Kang

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Manganese oxide particles with nanometre and several micrometre sizes were prepared by spray pyrolysis from aqueous and polymeric spray solutions. The LiMn2O4 particles prepared from Mn2O3 particles obtained from an aqueous solution with a manganese nitrate precursor had micrometre sizes and a spherical shape. On the other hand, the LiMn2O4 particles prepared from nano-sized Mn2O3 particles obtained from polymeric spray solutions had a fine size, a narrow size distribution, and regular morphology irrespective of the type of manganese precursors. The discharge capacities of the LiMn2O4 particles obtained from an aqueous spray solution with a manganese nitrate precursor dropped from 136 to 115 mAh/g by the 25 th cycle at a current density of 0.1 C. On the other hand, the discharge capacities of the LiMn2O4 particles obtained from a polymeric spray solution with a manganese nitrate precursor dropped from 121 to 105 mAh/g.

Original languageEnglish
Pages (from-to)138-143
Number of pages6
JournalJournal of Ceramic Processing Research
Volume11
Issue number2
Publication statusPublished - 2010 Jul 21
Externally publishedYes

Fingerprint

Manganese oxide
Manganese
Cathodes
Nitrates
Spray pyrolysis
Current density
lithium manganese oxide
manganese oxide

Keywords

  • Lithium manganate
  • Nano particle
  • Spray pyrolysis

ASJC Scopus subject areas

  • Ceramics and Composites

Cite this

The effect of manganese oxide precursors on the characteristics of LiMn2O4 cathode particles. / Ju, Seo Hee; Jang, Hee Chan; Lee, Man Jong; Kang, Yun Chan.

In: Journal of Ceramic Processing Research, Vol. 11, No. 2, 21.07.2010, p. 138-143.

Research output: Contribution to journalArticle

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AB - Manganese oxide particles with nanometre and several micrometre sizes were prepared by spray pyrolysis from aqueous and polymeric spray solutions. The LiMn2O4 particles prepared from Mn2O3 particles obtained from an aqueous solution with a manganese nitrate precursor had micrometre sizes and a spherical shape. On the other hand, the LiMn2O4 particles prepared from nano-sized Mn2O3 particles obtained from polymeric spray solutions had a fine size, a narrow size distribution, and regular morphology irrespective of the type of manganese precursors. The discharge capacities of the LiMn2O4 particles obtained from an aqueous spray solution with a manganese nitrate precursor dropped from 136 to 115 mAh/g by the 25 th cycle at a current density of 0.1 C. On the other hand, the discharge capacities of the LiMn2O4 particles obtained from a polymeric spray solution with a manganese nitrate precursor dropped from 121 to 105 mAh/g.

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