The effects of nitrogen bonding on hardness of AlN/CrN multilayer hard coatings

Sang Won Yoon, Jong Hyun Seo, Keun Hwa Chae, Jong Keuk Park, Jong Han Song, Vickram Jayaram, Kon Bae Lee, Tae Yeon Seong, Hoon-Kwon, Jae Pyoung Ahn

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

AlN/CrN multilayer hard coatings with various bilayer thicknesses were fabricated by a reactive sputtering process. The microstructural and mechanical characterizations of multilayer coatings were investigated through transmission electron microscope (TEM) observations and the hardness measurements by nano indentation. In particular, the variation of chemical bonding states of the bilayer nitrides was elucidated by near edge X-ray absorption fine structure (NEXAFS) spectroscopy. Many broken nitrogen bonds were formed by decreasing the bilayer thickness of AlN/CrN multilayer coatings. Existence of optimum AlN/CrN multilayer coatings thickness for maximum hardness could be explained by the competition of softening by the formation of broken nitrogen bonds and strengthening induced by decreasing bilayer thickness.

Original languageEnglish
Pages (from-to)1476-1479
Number of pages4
JournalJournal of Nanoscience and Nanotechnology
Volume12
Issue number2
DOIs
Publication statusPublished - 2012 Jun 5

Fingerprint

Hard coatings
Hardness
Multilayers
Nitrogen
hardness
X-Ray Absorption Spectroscopy
coatings
nitrogen
Coatings
Electrons
X ray absorption near edge structure spectroscopy
Reactive sputtering
Nanoindentation
nanoindentation
Nitrides
softening
nitrides
Electron microscopes
electron microscopes
sputtering

Keywords

  • AlN/CrN
  • Bilayer Thickness
  • Broken Nitrogen Bond
  • Multilayer Hard Coating
  • NEXAFS

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Chemistry(all)
  • Materials Science(all)
  • Bioengineering
  • Biomedical Engineering

Cite this

Yoon, S. W., Seo, J. H., Chae, K. H., Park, J. K., Song, J. H., Jayaram, V., ... Ahn, J. P. (2012). The effects of nitrogen bonding on hardness of AlN/CrN multilayer hard coatings. Journal of Nanoscience and Nanotechnology, 12(2), 1476-1479. https://doi.org/10.1166/jnn.2012.4699

The effects of nitrogen bonding on hardness of AlN/CrN multilayer hard coatings. / Yoon, Sang Won; Seo, Jong Hyun; Chae, Keun Hwa; Park, Jong Keuk; Song, Jong Han; Jayaram, Vickram; Lee, Kon Bae; Seong, Tae Yeon; Hoon-Kwon; Ahn, Jae Pyoung.

In: Journal of Nanoscience and Nanotechnology, Vol. 12, No. 2, 05.06.2012, p. 1476-1479.

Research output: Contribution to journalArticle

Yoon, SW, Seo, JH, Chae, KH, Park, JK, Song, JH, Jayaram, V, Lee, KB, Seong, TY, Hoon-Kwon & Ahn, JP 2012, 'The effects of nitrogen bonding on hardness of AlN/CrN multilayer hard coatings', Journal of Nanoscience and Nanotechnology, vol. 12, no. 2, pp. 1476-1479. https://doi.org/10.1166/jnn.2012.4699
Yoon, Sang Won ; Seo, Jong Hyun ; Chae, Keun Hwa ; Park, Jong Keuk ; Song, Jong Han ; Jayaram, Vickram ; Lee, Kon Bae ; Seong, Tae Yeon ; Hoon-Kwon ; Ahn, Jae Pyoung. / The effects of nitrogen bonding on hardness of AlN/CrN multilayer hard coatings. In: Journal of Nanoscience and Nanotechnology. 2012 ; Vol. 12, No. 2. pp. 1476-1479.
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