The preparation of SnO2 powders using polyol process and its gas sensing characteristics

Ji Hye Park, Jong Heun Lee

Research output: Contribution to journalArticle

Abstract

This study examined the gas sensing characteristics of nanocrystalline SnO2 powders prepared using the polyol process. A homogeneous Sn-precursor was prepared by heating a diethylene glycol solution containing SnCl2 and Poly Vinyl Pyrrolidone (PVP) at 200 °C for 5 h, which was then converted to SnO2 powders by heat treatment at 600 °C for 3 h. The size of the primary particles and agglomerates were dependent on [SnCl2]/[PVP] and the use of a nucleating agent PtCl4. In pure SnO2 form, the sensor prepared from the stock solution containing [SnCl2]/[PVP] = 1/0.6 showed selective detection to 200 ppm CH3COCH3 in the presence of C2H5OH, C3H8, and CO. The addition of 10 ppm PtCl4 significantly enhanced the responses to CH3COCH3 and C2H5OH. This was attributed to the decrease in particle size and agglomeration as well as to the catalytic effect of Pt.

Original languageEnglish
Pages (from-to)878-882
Number of pages5
JournalSensor Letters
Volume6
Issue number6
DOIs
Publication statusPublished - 2008 Dec 1

Fingerprint

Polyols
Nanocrystalline powders
Powders
preparation
agglomeration
Glycols
Gases
gases
glycols
heat treatment
Agglomeration
Particle size
Heat treatment
Heating
heating
sensors
Sensors

Keywords

  • Gas sensor
  • Polyol process
  • Sensitivity
  • SnO

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Atomic and Molecular Physics, and Optics

Cite this

The preparation of SnO2 powders using polyol process and its gas sensing characteristics. / Park, Ji Hye; Lee, Jong Heun.

In: Sensor Letters, Vol. 6, No. 6, 01.12.2008, p. 878-882.

Research output: Contribution to journalArticle

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