Thermally reduced rGO-wrapped CoP/Co2P hybrid microflower as an electrocatalyst for hydrogen evolution reaction

Taek Seung Kim, Hee Jo Song, Mushtaq Ahmad Dar, Hyun Woo Shim, Dong-Wan Kim

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Cobalt phosphides (CoPx) are potential candidates for use as high-efficiency hydrogen evolution reaction electrocatalysts that can replace noble metals, such as Pt. Typically, CoPx can be synthesized by phosphidation with Co-based precursors such as oxides or hydroxides. In this study, we propose a new strategy for synthesizing CoPx through the thermal reduction in cobalt phosphate (Co3(PO4)2). A reduced graphene oxide-wrapped CoP/Co2P hybrid microflower was successfully synthesized by a facile coprecipitation method in a Co3(PO4)2 matrix, followed by a thermal reduction process. Co3(PO4)2 can be transformed to CoP/Co2P by treatment at 700°C for 1 hour, maintaining the original particle morphology with the assistance of reduced graphene oxide (rGO). In a 0.5 mol/L H2SO4 solution, the rGO-CoP/Co2P microflower catalyzes the hydrogen evolution reaction with an overpotential of 156 mV at a current density of 10 mA cm-2, a Tafel slope of 53.8 mV dec-1, and good stability as observed through long-term CV and chronoamperometry tests.

Original languageEnglish
JournalJournal of the American Ceramic Society
DOIs
Publication statusAccepted/In press - 2018 Jan 1

Fingerprint

Graphite
Electrocatalysts
Oxides
Graphene
Hydrogen
oxide
hydrogen
Cobalt
cobalt
Hydroxides
Chronoamperometry
Precious metals
Coprecipitation
hydroxide
Phosphates
Current density
phosphate
matrix
metal
Hot Temperature

Keywords

  • Catalysts/catalysis
  • Cobalt/cobalt compounds
  • Graphene oxide
  • Hydrogen evolution reaction
  • Phosphates

ASJC Scopus subject areas

  • Ceramics and Composites
  • Geology
  • Geochemistry and Petrology
  • Materials Chemistry

Cite this

Thermally reduced rGO-wrapped CoP/Co2P hybrid microflower as an electrocatalyst for hydrogen evolution reaction. / Kim, Taek Seung; Song, Hee Jo; Dar, Mushtaq Ahmad; Shim, Hyun Woo; Kim, Dong-Wan.

In: Journal of the American Ceramic Society, 01.01.2018.

Research output: Contribution to journalArticle

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abstract = "Cobalt phosphides (CoPx) are potential candidates for use as high-efficiency hydrogen evolution reaction electrocatalysts that can replace noble metals, such as Pt. Typically, CoPx can be synthesized by phosphidation with Co-based precursors such as oxides or hydroxides. In this study, we propose a new strategy for synthesizing CoPx through the thermal reduction in cobalt phosphate (Co3(PO4)2). A reduced graphene oxide-wrapped CoP/Co2P hybrid microflower was successfully synthesized by a facile coprecipitation method in a Co3(PO4)2 matrix, followed by a thermal reduction process. Co3(PO4)2 can be transformed to CoP/Co2P by treatment at 700°C for 1 hour, maintaining the original particle morphology with the assistance of reduced graphene oxide (rGO). In a 0.5 mol/L H2SO4 solution, the rGO-CoP/Co2P microflower catalyzes the hydrogen evolution reaction with an overpotential of 156 mV at a current density of 10 mA cm-2, a Tafel slope of 53.8 mV dec-1, and good stability as observed through long-term CV and chronoamperometry tests.",
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AU - Dar, Mushtaq Ahmad

AU - Shim, Hyun Woo

AU - Kim, Dong-Wan

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AB - Cobalt phosphides (CoPx) are potential candidates for use as high-efficiency hydrogen evolution reaction electrocatalysts that can replace noble metals, such as Pt. Typically, CoPx can be synthesized by phosphidation with Co-based precursors such as oxides or hydroxides. In this study, we propose a new strategy for synthesizing CoPx through the thermal reduction in cobalt phosphate (Co3(PO4)2). A reduced graphene oxide-wrapped CoP/Co2P hybrid microflower was successfully synthesized by a facile coprecipitation method in a Co3(PO4)2 matrix, followed by a thermal reduction process. Co3(PO4)2 can be transformed to CoP/Co2P by treatment at 700°C for 1 hour, maintaining the original particle morphology with the assistance of reduced graphene oxide (rGO). In a 0.5 mol/L H2SO4 solution, the rGO-CoP/Co2P microflower catalyzes the hydrogen evolution reaction with an overpotential of 156 mV at a current density of 10 mA cm-2, a Tafel slope of 53.8 mV dec-1, and good stability as observed through long-term CV and chronoamperometry tests.

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