Thermally stable antireflective coatings based on nanoporous organosilicate thin films

Suhan Kim, Jinhan Cho, Kookheon Char

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

Thermally stable nanoporous organosilicate thin films were realized by the microphase separation of pore-generating polymers mixed with an organosilicate matrix to be antireflective coatings (ARCs), for which a thin film with a refractive index (n) of 1.23 for zero reflection is required. The refractive index of such nanoporous organosilicate films can be tuned from 1.39 down to 1.23 by incorporating nanopores within the films. With a nanoporous single layer with n ∼ 1.23, the light transmittance of the glass above 99.8% was achieved in the visible range (λ ∼ 550 nm). To overcome the limitation on the narrow wavelength for high transmittance imposed by a single antireflective nanoporous thin film, bilayer thin films with different refractive indices were prepared by placing a high refractive index layer with a refractive index of 1.45 below the nanoporous thin film. UV-vis transmittance of a glass coated with the bilayer films was compared with nanoporous single-layer films and it is demonstrated that the novel broadband antireflection coatings in a wide range of visible wavelength can be easily obtained by the organosilicate bilayer thin films described in this study. Also, ARCs developed in this study demonstrate excellent AR durability owing to the hydrophobic nature of the organosilicate matrix.

Original languageEnglish
Pages (from-to)6737-6743
Number of pages7
JournalLangmuir
Volume23
Issue number12
DOIs
Publication statusPublished - 2007 Jun 5
Externally publishedYes

Fingerprint

Refractometry
Refractive index
coatings
Thin films
Coatings
refractivity
thin films
transmittance
Glass
Nanopores
Microphase separation
Wavelength
Antireflection coatings
glass
antireflection coatings
matrices
durability
Polymers
wavelengths
Durability

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

Cite this

Thermally stable antireflective coatings based on nanoporous organosilicate thin films. / Kim, Suhan; Cho, Jinhan; Char, Kookheon.

In: Langmuir, Vol. 23, No. 12, 05.06.2007, p. 6737-6743.

Research output: Contribution to journalArticle

Kim, Suhan ; Cho, Jinhan ; Char, Kookheon. / Thermally stable antireflective coatings based on nanoporous organosilicate thin films. In: Langmuir. 2007 ; Vol. 23, No. 12. pp. 6737-6743.
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