Thermally stable maleimide copolymer for second-order nonlinear optics

Dong Hoon Choi; Sangyup Song; Taek Seung Lee; Soo Young Park; Nakjoong Kim

doi:10.1002/(SICI)1097-4628(19960103)59:1<9::AID-APP2>3.0.CO;2-Y

Thermally stable maleimide copolymer for second-order nonlinear optics

Dong Hoon Choi, Sangyup Song, Taek Seung Lee, Soo Young Park, Nakjoong Kim

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Second-order nonlinear optical copolymer containing p-hydroxyphenyl maleimide as a comonomer was newly synthesized. Second-order nonlinear optical properties of the poled films were investigated in terms of the second harmonic generation (SHG) and linear electrooptic (EO) coefficient measurement. SHG coefficient, d₃₃ was found to be 14 pm/V at the fundamental wavelength of 1064 nm and EO coefficient, r₃₃ was found to be 25-30 pm/V at 633 nm wavelength. To prevent the orientational relaxation of poled polymer, the thermal crosslink reaction was induced using diisocyanate as a crosslinker between the side chains themselves. Temporal stabilities of second-order NLO coefficients of crosslinked polymer systems were proved much better than that of guest-host system or other side chain polymers.

Original language	English
Pages (from-to)	9-14
Number of pages	6
Journal	Journal of Applied Polymer Science
Volume	59
Issue number	1
DOIs	https://doi.org/10.1002/(SICI)1097-4628(19960103)59:1<9::AID-APP2>3.0.CO;2-Y
Publication status	Published - 1996 Jan 3
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Surfaces, Coatings and Films
Polymers and Plastics
Materials Chemistry

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10.1002/(SICI)1097-4628(19960103)59:1<9::AID-APP2>3.0.CO;2-Y

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abstract = "Second-order nonlinear optical copolymer containing p-hydroxyphenyl maleimide as a comonomer was newly synthesized. Second-order nonlinear optical properties of the poled films were investigated in terms of the second harmonic generation (SHG) and linear electrooptic (EO) coefficient measurement. SHG coefficient, d33 was found to be 14 pm/V at the fundamental wavelength of 1064 nm and EO coefficient, r33 was found to be 25-30 pm/V at 633 nm wavelength. To prevent the orientational relaxation of poled polymer, the thermal crosslink reaction was induced using diisocyanate as a crosslinker between the side chains themselves. Temporal stabilities of second-order NLO coefficients of crosslinked polymer systems were proved much better than that of guest-host system or other side chain polymers.",

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AU - Choi, Dong Hoon

AU - Song, Sangyup

AU - Lee, Taek Seung

AU - Park, Soo Young

AU - Kim, Nakjoong

PY - 1996/1/3

Y1 - 1996/1/3

N2 - Second-order nonlinear optical copolymer containing p-hydroxyphenyl maleimide as a comonomer was newly synthesized. Second-order nonlinear optical properties of the poled films were investigated in terms of the second harmonic generation (SHG) and linear electrooptic (EO) coefficient measurement. SHG coefficient, d33 was found to be 14 pm/V at the fundamental wavelength of 1064 nm and EO coefficient, r33 was found to be 25-30 pm/V at 633 nm wavelength. To prevent the orientational relaxation of poled polymer, the thermal crosslink reaction was induced using diisocyanate as a crosslinker between the side chains themselves. Temporal stabilities of second-order NLO coefficients of crosslinked polymer systems were proved much better than that of guest-host system or other side chain polymers.

AB - Second-order nonlinear optical copolymer containing p-hydroxyphenyl maleimide as a comonomer was newly synthesized. Second-order nonlinear optical properties of the poled films were investigated in terms of the second harmonic generation (SHG) and linear electrooptic (EO) coefficient measurement. SHG coefficient, d33 was found to be 14 pm/V at the fundamental wavelength of 1064 nm and EO coefficient, r33 was found to be 25-30 pm/V at 633 nm wavelength. To prevent the orientational relaxation of poled polymer, the thermal crosslink reaction was induced using diisocyanate as a crosslinker between the side chains themselves. Temporal stabilities of second-order NLO coefficients of crosslinked polymer systems were proved much better than that of guest-host system or other side chain polymers.

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Thermally stable maleimide copolymer for second-order nonlinear optics

Abstract

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