Three-dimensional thermal stress analysis of the re-oxidized Ni-YSZ anode functional layer in solid oxide fuel cells

Jun Woo Kim, Kiho Bae, Hyun Joong Kim, Ji won Son, Namkeun Kim, Stefan Stenfelt, Fritz B. Prinz, Joon Hyung Shim

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Nickel-yttria-stabilized zirconia (Ni-YSZ) cermet is widely used as an anode material in solid oxide fuel cells (SOFCs); however, Ni re-oxidation causes critical problems due to volume expansion, which causes high thermal stress. We fabricated a Ni-YSZ anode functional layer (AFL), which is an essential component in high-performance SOFCs, and re-oxidized it to investigate the related three-dimensional (3D) microstructural and thermo-mechanical effects. A 3D model of the re-oxidized AFL was generated using focused ion beam-scanning electron microscope (FIB-SEM) tomography. Re-oxidation of the Ni phase caused significant volumetric expansion, which was confirmed via image analysis and calculation of the volume fraction, connectivity, and two-phase boundary density. Finite element analysis (FEA) with simulated heating to 500–900 °C confirmed that the thermal stress in re-oxidized Ni-YSZ is concentrated at the boundaries between YSZ and re-oxidized NiO (nickel oxide). NiO is subjected to more stress than YSZ. Stress exceeding the fracture stress of 8 mol% YSZ appears primarily at 800 °C or higher. The stress is also more severe near the electrolyte-anode boundary than in the Ni-YSZ cermet and the YSZ regions. This may be responsible for the electrolyte membrane delamination and fracture that are observed during high-temperature operation.

Original languageEnglish
Pages (from-to)148-154
Number of pages7
JournalJournal of Alloys and Compounds
Volume752
DOIs
Publication statusPublished - 2018 Jul 5

Fingerprint

Yttria stabilized zirconia
Solid oxide fuel cells (SOFC)
Nickel
Stress analysis
Thermal stress
Cermet Cements
Anodes
Nickel oxide
Electrolytes
High temperature operations
Oxidation
Focused ion beams
Phase boundaries
Delamination
Image analysis
Tomography
Volume fraction
Electron microscopes
Membranes
Scanning

Keywords

  • 3D reconstruction
  • Finite element analysis
  • Focused ion beam-scanning electron microscope
  • NiO-YSZ anode functional layer
  • Thermal stress

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Three-dimensional thermal stress analysis of the re-oxidized Ni-YSZ anode functional layer in solid oxide fuel cells. / Kim, Jun Woo; Bae, Kiho; Kim, Hyun Joong; Son, Ji won; Kim, Namkeun; Stenfelt, Stefan; Prinz, Fritz B.; Shim, Joon Hyung.

In: Journal of Alloys and Compounds, Vol. 752, 05.07.2018, p. 148-154.

Research output: Contribution to journalArticle

Kim, Jun Woo ; Bae, Kiho ; Kim, Hyun Joong ; Son, Ji won ; Kim, Namkeun ; Stenfelt, Stefan ; Prinz, Fritz B. ; Shim, Joon Hyung. / Three-dimensional thermal stress analysis of the re-oxidized Ni-YSZ anode functional layer in solid oxide fuel cells. In: Journal of Alloys and Compounds. 2018 ; Vol. 752. pp. 148-154.
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AU - Stenfelt, Stefan

AU - Prinz, Fritz B.

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AB - Nickel-yttria-stabilized zirconia (Ni-YSZ) cermet is widely used as an anode material in solid oxide fuel cells (SOFCs); however, Ni re-oxidation causes critical problems due to volume expansion, which causes high thermal stress. We fabricated a Ni-YSZ anode functional layer (AFL), which is an essential component in high-performance SOFCs, and re-oxidized it to investigate the related three-dimensional (3D) microstructural and thermo-mechanical effects. A 3D model of the re-oxidized AFL was generated using focused ion beam-scanning electron microscope (FIB-SEM) tomography. Re-oxidation of the Ni phase caused significant volumetric expansion, which was confirmed via image analysis and calculation of the volume fraction, connectivity, and two-phase boundary density. Finite element analysis (FEA) with simulated heating to 500–900 °C confirmed that the thermal stress in re-oxidized Ni-YSZ is concentrated at the boundaries between YSZ and re-oxidized NiO (nickel oxide). NiO is subjected to more stress than YSZ. Stress exceeding the fracture stress of 8 mol% YSZ appears primarily at 800 °C or higher. The stress is also more severe near the electrolyte-anode boundary than in the Ni-YSZ cermet and the YSZ regions. This may be responsible for the electrolyte membrane delamination and fracture that are observed during high-temperature operation.

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