Titanatranes containing tetradentate ligands with controlled steric hindrance

Sang deok Mun, Junseong Lee, So Han Kim, Younjin Hong, Young ho Ko, Young Kook Shin, Jeong Hak Lim, Chang Seop Hong, Youngkyu Do, Youngjo Kim

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

New monomeric titanatranes {A figure is presented} (Ar = 2,6-di-i-Pr-phenyl; x = 0, 5; x = 1, 6; x = 2, 7; x = 3, 8) were synthesized from the corresponding tetradentate ligands 1-4, respectively, using an equimolar mixture of Ti(O-i-Pr)4 and 2,6-di-i-Pr-phenol. These compounds show the catalytic activity for the ring opening polymerization of l-lactide.

Original languageEnglish
Pages (from-to)3519-3525
Number of pages7
JournalJournal of Organometallic Chemistry
Volume692
Issue number16
DOIs
Publication statusPublished - 2007 Jul 15

Keywords

  • Polylactide
  • Ring opening polymerization
  • Tetradentate ligand
  • Titanium
  • X-ray structure

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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  • Cite this

    Mun, S. D., Lee, J., Kim, S. H., Hong, Y., Ko, Y. H., Shin, Y. K., Lim, J. H., Hong, C. S., Do, Y., & Kim, Y. (2007). Titanatranes containing tetradentate ligands with controlled steric hindrance. Journal of Organometallic Chemistry, 692(16), 3519-3525. https://doi.org/10.1016/j.jorganchem.2007.04.031