Transition metal-mediated metathesis between P–C and M–C bonds: Beyond a side reaction

Yong Ho Lee, Bill Morandi

Research output: Contribution to journalReview articlepeer-review

20 Citations (Scopus)

Abstract

Phosphine ligands often play an important role in controlling reactivity and selectivity in transition metal catalyzed reactions. However, one common drawback of the phosphine ligands is the undesired occurrence of an interchange between P bound aryl and M bound aryl or alkyl groups in the catalytic cycle. This results in the formation of undesirable coupling products as well as changes in catalyst structure through the replacement of the phosphine ligand. This review discusses approaches to understand this metathesis reaction between P–C and M–C and its productive application in catalytic reactions.

Original languageEnglish
Pages (from-to)96-118
Number of pages23
JournalCoordination Chemistry Reviews
Volume386
DOIs
Publication statusPublished - 2019 May 1
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'Transition metal-mediated metathesis between P–C and M–C bonds: Beyond a side reaction'. Together they form a unique fingerprint.

Cite this