Tributyl tetradecyl phosphonium chloride for biofouling control in reverse osmosis processes

Taek Seung Kim, Hee-Deung Park

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Biofouling is a major operational problem in reverse osmosis (RO) processes. Recently, direct dosing of non-oxidizing biocides into RO vessels has been attempted to effectively alleviate biofouling. Tributyl tetradecyl phosphonium chloride (TTPC) is an efficient non-oxidizing biocide, but its application to RO processes has been rarely studied. This study aimed to evaluate the applicability of TTPC to RO processes. Scanning electron microscopy and Fourier transform infrared spectroscopy analyses confirmed that the RO membrane was resistant to morphological and chemical damage up to 100,000. mg/L TTPC. Rejection of TTPC determined by a dead-end filtration unit was greater than 99.58%. Furthermore, low concentrations of TTPC (20-40. mg/L) had antimicrobial and antibiofilm properties, as determined by minimum inhibitory concentration, minimum bactericidal concentration, and evaluation of static biofilm formation. TTPC also effectively removed biofilms that had already formed on RO membranes. Given these properties of TTPC, this study demonstrates the potential for TTPC as a biocide controlling biofouling in RO processes.

Original languageEnglish
Pages (from-to)39-46
Number of pages8
JournalDesalination
Volume372
DOIs
Publication statusPublished - 2015 Sep 5

Fingerprint

Biofouling
biofouling
Reverse osmosis
chloride
Biocides
Disinfectants
Osmosis membranes
Biofilms
pesticide
biofilm
membrane
tributylmethyl phosphonium chloride
reverse osmosis
Fourier transform infrared spectroscopy
FTIR spectroscopy
vessel
scanning electron microscopy
Scanning electron microscopy
damage

Keywords

  • Biocide
  • Biofouling
  • Non-oxidizing biocide
  • Reverse osmosis
  • Tributyl tetradecyl phosphonium chloride

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Mechanical Engineering
  • Chemistry(all)
  • Materials Science(all)
  • Water Science and Technology

Cite this

Tributyl tetradecyl phosphonium chloride for biofouling control in reverse osmosis processes. / Kim, Taek Seung; Park, Hee-Deung.

In: Desalination, Vol. 372, 05.09.2015, p. 39-46.

Research output: Contribution to journalArticle

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