TY - JOUR
T1 - Tuning the interface between poly(vinylidene fluoride)/UV-curable polysilsesquioxane hybrid composites
T2 - Compatibility, thermal, mechanical, electrical, and surface properties
AU - Cho, Kie Yong
AU - Lee, Albert S.
AU - Jeon, Hyeonyeol
AU - Park, Sang Hee
AU - Jang, Munjeong
AU - Yoon, Ho Gyu
AU - Hong, Soon Man
AU - Baek, Kyung Youl
AU - Hwang, Seung Sang
N1 - Funding Information:
This work was supported by the Industrial Strategic Technology Development Program, 10043880 , Development of manufacturing technology of fluorinated material for energy device, solar cell, with high durability for more than 20 years, funded by the Ministry of Trade, Industry & Energy (MI, Korea), and partially supported by a grant from Materials Architecturing Research Center of Korea Institute of Science and Technology .
Publisher Copyright:
© 2015 Elsevier Ltd. All rights reserved.
Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.
PY - 2015/10/23
Y1 - 2015/10/23
N2 - Compatible hybrid composites (PVLPMA) comprising of poly(vinylidene fluoride) (PVDF) and UV-curable ladder-like polysilsesquioxane (LPMASQ) were investigated for maximizing synergetic effects in various properties. The PVDF fluoropolymer was found to be well-incorporated with the LPMASQ inorganic filler because of good hydrogen-bonding, and the compatibility rigorously investigated by FT-IR, DSC, and WAXS studies. In addition, the crosslinkable function arising from the methacryl-group of the LPMASQ inorganic filler with the aid of the radical source was evaluated from the analysis of various properties. After UV-crosslinking, PVLPMA hybrid composites showcased enhanced mechanical properties such as elastic modulus, surface modulus, and surface hardness with accordance to the increasing the LPMASQ quantity. In addition, hydrophobicity was observed through the increase in the water contact angle up to 115°, a value much larger than that of neat PVDF and cured LPMASQ. Furthermore, the enhanced electrical stability of PVLPMA hybrid composites was obtained through examination of dielectric properties and breakdown strength in comparison to neat PVDF. These PVDF-LPMASQ organic-inorganic compatible hybrid composites with enhanced properties arising from the good compatibility and synergetic effects can be applicable in the various fields supplanting neat PVDF.
AB - Compatible hybrid composites (PVLPMA) comprising of poly(vinylidene fluoride) (PVDF) and UV-curable ladder-like polysilsesquioxane (LPMASQ) were investigated for maximizing synergetic effects in various properties. The PVDF fluoropolymer was found to be well-incorporated with the LPMASQ inorganic filler because of good hydrogen-bonding, and the compatibility rigorously investigated by FT-IR, DSC, and WAXS studies. In addition, the crosslinkable function arising from the methacryl-group of the LPMASQ inorganic filler with the aid of the radical source was evaluated from the analysis of various properties. After UV-crosslinking, PVLPMA hybrid composites showcased enhanced mechanical properties such as elastic modulus, surface modulus, and surface hardness with accordance to the increasing the LPMASQ quantity. In addition, hydrophobicity was observed through the increase in the water contact angle up to 115°, a value much larger than that of neat PVDF and cured LPMASQ. Furthermore, the enhanced electrical stability of PVLPMA hybrid composites was obtained through examination of dielectric properties and breakdown strength in comparison to neat PVDF. These PVDF-LPMASQ organic-inorganic compatible hybrid composites with enhanced properties arising from the good compatibility and synergetic effects can be applicable in the various fields supplanting neat PVDF.
KW - Fluorinated polymers
KW - Hybrid composites
KW - UV-curing
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U2 - 10.1016/j.polymer.2015.09.031
DO - 10.1016/j.polymer.2015.09.031
M3 - Article
AN - SCOPUS:84942580042
SN - 0032-3861
VL - 77
SP - 167
EP - 176
JO - Polymer (United Kingdom)
JF - Polymer (United Kingdom)
ER -