Abstract
The ultrafast charge generation process in organic solar cell devices is investigated by transient reflection spectroscopy on five state-of-the-art bulk heterojunction systems. The charge generation process in operating devices is found to be a combination of an ultrafast generation mechanism over several hundred femtoseconds and a slow process from picoseconds to nanoseconds, limited by exciton diffusion dynamics. In addition, the lack of electric field dependence in the charge dynamics rules out geminate recombination as an important loss mechanism.
Original language | English |
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Pages (from-to) | 2036-2041 |
Number of pages | 6 |
Journal | Advanced Materials |
Volume | 27 |
Issue number | 12 |
DOIs | |
Publication status | Published - 2015 Mar 25 |
Externally published | Yes |
Keywords
- bulk heterojunctions
- organic solar cells
- transient reflection spectroscopy
- ultrafast charge transfer
ASJC Scopus subject areas
- Materials Science(all)
- Mechanics of Materials
- Mechanical Engineering