Ultrasound-assisted heterogeneous Fenton-like process for bisphenol A removal at neutral pH using hierarchically structured manganese dioxide/biochar nanocomposites as catalysts

Kyung Won Jung, Seon Yong Lee, Young Jae Lee, Jae Woo Choi

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2 Citations (Scopus)

Abstract

Bisphenol A (BPA) is an important emerging contaminant with endocrine-disrupting potential that has frequently been detected in aquatic environments. In this study, two types of hierarchically structured manganese dioxide/biochar nanocomposites (MnO 2 /BCs) were prepared for the first time via facile hydrothermal synthesis. The hydrothermal reaction was maintained at 100 °C for 6 h or 12 h, after which an ultrasound-assisted heterogeneous Fenton-like process was used to catalyze the removal of BPA under neutral pH condition. The characterization results indicated that MnO 2 nanoparticles were successfully formed on the nanocomposite surfaces and had flower-like (δ-MnO 2 , 6 h) and urchin-like (α-MnO 2 , 12 h) morphology. This enabled a significant improvement in the catalytic activity of BPA removal by the reversible redox reaction. A series of experiments confirmed that the crystalline properties of the nanocomposites affected their catalytic activity. In particular, the α-MnO 2 /BCs exhibited catalytic activity in the ultrasound-assisted heterogeneous Fenton-like process and completely removed BPA within 20 min under the following conditions: [BPA] 0 = 100 μM; [H 2 O 2 ] 0 = 10 mM; [catalyst] 0 = 0.5 g/L; ultrasound = 20 kHz (130 W) at 40% amplitude; pH = 7.0 ± 0.1; and temperature = 25 ± 1 °C. This efficiency may have been due to the synergistic effect of ultrasound and α-MnO 2 /BCs, which simultaneously induce the effective generation of reactive free radicals and increase the mass transfer rate at the solid-liquid interface. Overall, these results demonstrated that hierarchical urchin-like α-MnO 2 /BCs have significant potential as an efficient and low-cost catalyst in ultrasound-assisted heterogeneous Fenton-like systems.

Original languageEnglish
Pages (from-to)22-28
Number of pages7
JournalUltrasonics Sonochemistry
Volume57
DOIs
Publication statusPublished - 2019 Oct 1

Fingerprint

Nanocomposites
bisphenols
dioxides
Manganese
manganese
nanocomposites
Ultrasonics
catalysts
Catalysts
catalytic activity
Catalyst activity
disrupting
Redox reactions
Hydrothermal synthesis
liquid-solid interfaces
Free radicals
Nanoparticles
free radicals
Oxidation-Reduction
mass transfer

Keywords

  • Biochar
  • Bisphenol A
  • Nanocomposites
  • Ultrasound-assisted heterogeneous Fenton-like
  • Urchin-like α-MnO

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Radiology Nuclear Medicine and imaging
  • Acoustics and Ultrasonics

Cite this

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title = "Ultrasound-assisted heterogeneous Fenton-like process for bisphenol A removal at neutral pH using hierarchically structured manganese dioxide/biochar nanocomposites as catalysts",
abstract = "Bisphenol A (BPA) is an important emerging contaminant with endocrine-disrupting potential that has frequently been detected in aquatic environments. In this study, two types of hierarchically structured manganese dioxide/biochar nanocomposites (MnO 2 /BCs) were prepared for the first time via facile hydrothermal synthesis. The hydrothermal reaction was maintained at 100 °C for 6 h or 12 h, after which an ultrasound-assisted heterogeneous Fenton-like process was used to catalyze the removal of BPA under neutral pH condition. The characterization results indicated that MnO 2 nanoparticles were successfully formed on the nanocomposite surfaces and had flower-like (δ-MnO 2 , 6 h) and urchin-like (α-MnO 2 , 12 h) morphology. This enabled a significant improvement in the catalytic activity of BPA removal by the reversible redox reaction. A series of experiments confirmed that the crystalline properties of the nanocomposites affected their catalytic activity. In particular, the α-MnO 2 /BCs exhibited catalytic activity in the ultrasound-assisted heterogeneous Fenton-like process and completely removed BPA within 20 min under the following conditions: [BPA] 0 = 100 μM; [H 2 O 2 ] 0 = 10 mM; [catalyst] 0 = 0.5 g/L; ultrasound = 20 kHz (130 W) at 40{\%} amplitude; pH = 7.0 ± 0.1; and temperature = 25 ± 1 °C. This efficiency may have been due to the synergistic effect of ultrasound and α-MnO 2 /BCs, which simultaneously induce the effective generation of reactive free radicals and increase the mass transfer rate at the solid-liquid interface. Overall, these results demonstrated that hierarchical urchin-like α-MnO 2 /BCs have significant potential as an efficient and low-cost catalyst in ultrasound-assisted heterogeneous Fenton-like systems.",
keywords = "Biochar, Bisphenol A, Nanocomposites, Ultrasound-assisted heterogeneous Fenton-like, Urchin-like α-MnO",
author = "Jung, {Kyung Won} and Lee, {Seon Yong} and Lee, {Young Jae} and Choi, {Jae Woo}",
year = "2019",
month = "10",
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language = "English",
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T1 - Ultrasound-assisted heterogeneous Fenton-like process for bisphenol A removal at neutral pH using hierarchically structured manganese dioxide/biochar nanocomposites as catalysts

AU - Jung, Kyung Won

AU - Lee, Seon Yong

AU - Lee, Young Jae

AU - Choi, Jae Woo

PY - 2019/10/1

Y1 - 2019/10/1

N2 - Bisphenol A (BPA) is an important emerging contaminant with endocrine-disrupting potential that has frequently been detected in aquatic environments. In this study, two types of hierarchically structured manganese dioxide/biochar nanocomposites (MnO 2 /BCs) were prepared for the first time via facile hydrothermal synthesis. The hydrothermal reaction was maintained at 100 °C for 6 h or 12 h, after which an ultrasound-assisted heterogeneous Fenton-like process was used to catalyze the removal of BPA under neutral pH condition. The characterization results indicated that MnO 2 nanoparticles were successfully formed on the nanocomposite surfaces and had flower-like (δ-MnO 2 , 6 h) and urchin-like (α-MnO 2 , 12 h) morphology. This enabled a significant improvement in the catalytic activity of BPA removal by the reversible redox reaction. A series of experiments confirmed that the crystalline properties of the nanocomposites affected their catalytic activity. In particular, the α-MnO 2 /BCs exhibited catalytic activity in the ultrasound-assisted heterogeneous Fenton-like process and completely removed BPA within 20 min under the following conditions: [BPA] 0 = 100 μM; [H 2 O 2 ] 0 = 10 mM; [catalyst] 0 = 0.5 g/L; ultrasound = 20 kHz (130 W) at 40% amplitude; pH = 7.0 ± 0.1; and temperature = 25 ± 1 °C. This efficiency may have been due to the synergistic effect of ultrasound and α-MnO 2 /BCs, which simultaneously induce the effective generation of reactive free radicals and increase the mass transfer rate at the solid-liquid interface. Overall, these results demonstrated that hierarchical urchin-like α-MnO 2 /BCs have significant potential as an efficient and low-cost catalyst in ultrasound-assisted heterogeneous Fenton-like systems.

AB - Bisphenol A (BPA) is an important emerging contaminant with endocrine-disrupting potential that has frequently been detected in aquatic environments. In this study, two types of hierarchically structured manganese dioxide/biochar nanocomposites (MnO 2 /BCs) were prepared for the first time via facile hydrothermal synthesis. The hydrothermal reaction was maintained at 100 °C for 6 h or 12 h, after which an ultrasound-assisted heterogeneous Fenton-like process was used to catalyze the removal of BPA under neutral pH condition. The characterization results indicated that MnO 2 nanoparticles were successfully formed on the nanocomposite surfaces and had flower-like (δ-MnO 2 , 6 h) and urchin-like (α-MnO 2 , 12 h) morphology. This enabled a significant improvement in the catalytic activity of BPA removal by the reversible redox reaction. A series of experiments confirmed that the crystalline properties of the nanocomposites affected their catalytic activity. In particular, the α-MnO 2 /BCs exhibited catalytic activity in the ultrasound-assisted heterogeneous Fenton-like process and completely removed BPA within 20 min under the following conditions: [BPA] 0 = 100 μM; [H 2 O 2 ] 0 = 10 mM; [catalyst] 0 = 0.5 g/L; ultrasound = 20 kHz (130 W) at 40% amplitude; pH = 7.0 ± 0.1; and temperature = 25 ± 1 °C. This efficiency may have been due to the synergistic effect of ultrasound and α-MnO 2 /BCs, which simultaneously induce the effective generation of reactive free radicals and increase the mass transfer rate at the solid-liquid interface. Overall, these results demonstrated that hierarchical urchin-like α-MnO 2 /BCs have significant potential as an efficient and low-cost catalyst in ultrasound-assisted heterogeneous Fenton-like systems.

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KW - Bisphenol A

KW - Nanocomposites

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KW - Urchin-like α-MnO

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