A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N 3)2]·MeCN (1·MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry