Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide

Sik Yoo Houng, Il Kim Jae, Namgeun Yang, Kwan Koh Eui, Je Geun Park, Seop Hong Chang

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A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N 3)2]·MeCN (1·MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.

Original languageEnglish
Pages (from-to)9054-9056
Number of pages3
JournalInorganic Chemistry
Issue number22
Publication statusPublished - 2007 Oct 29


ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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