Uniquely structured composite microspheres of metal sulfides and carbon with cubic nanorooms for highly efficient anode materials for sodium-ion batteries

Jin Koo Kim, Seung Keun Park, Jin Sung Park, Yun Chan Kang

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Metal sulfides are promising anode materials for high-performance sodium-ion batteries. However, their drastic volume variation and poor electrical conductivity during cycling result in poor performance, which is a major challenge. In this study, we report the facile and generalized aerosol-assisted synthesis of metal sulfide/C composite microspheres with cubic nanorooms (MeS x /C-NR) by employing NaCl as a washable template. We investigated the optimization method for synthesizing this novel nanostructure by controlling the synthesis conditions. In the case of MoS 2 /C-NR, which was selected as the main target material, few-layered MoS 2 nanosheets were successfully formed, and their restacking during cycling was prevented via incorporation with a dextrin-derived carbon matrix. Meso-/macropores generated by NaCl increased the affinity of MoS 2 /C-NR to the electrolyte, increasing the active surface area for electrochemical reaction and reducing the diffusion length of Na + without compromising the structural robustness. As a result, the MoS 2 /C-NR delivered a stable reversible capacity of 385 mA h g -1 for 350 cycles at a current density of 0.5 A g -1 and a high rate performance of 287 mA h g -1 at a current density of 7 A g -1 . This synthesis strategy can be utilized to prepare other porous metal sulfide/carbon composites, including FeS 2 /C-NR and SnS/C-NR, without much difficulty, which may be valuable for many other applications, including energy storage.

Original languageEnglish
Pages (from-to)2636-2645
Number of pages10
JournalJournal of Materials Chemistry A
Volume7
Issue number6
DOIs
Publication statusPublished - 2019 Jan 1

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Microspheres
Anodes
Metals
Sodium
Sulfides
Ions
Carbon
Composite materials
Current density
Nanosheets
Aerosols
Energy storage
Electrolytes
Nanostructures
carbon sulfide

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Uniquely structured composite microspheres of metal sulfides and carbon with cubic nanorooms for highly efficient anode materials for sodium-ion batteries. / Kim, Jin Koo; Park, Seung Keun; Park, Jin Sung; Kang, Yun Chan.

In: Journal of Materials Chemistry A, Vol. 7, No. 6, 01.01.2019, p. 2636-2645.

Research output: Contribution to journalArticle

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