Vapor-liquid equilibrium correlations for systems containing amines using a lattice fluid equation of state with hydrogen bonding

Alexander Breitholz, Ki Pung Yoo, Jong Sung Lim, Chul Soo Lee, Jeong Won Kang

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The nonrandom lattice equation of state with hydrogen bonding (NLF-HB EOS) was examined for the correlation of vapor-liquid equilibria (VLE) for binary amine and hydrocarbon mixture at various temperatures. For these mixtures, the consideration of hydrogen bondings in the lattice equation of state clearly improves the prediction for VLE. The amines were divided into four groups due to the different strength of the hydrogen bonding. For all groups, different hydrogen bonding parameters were obtained and evaluated. The effects of varying hydrogen bonding energies for NLF-HB EOS are discussed. For systems containing lower amines, the NLF-HB EOS showed excellent agreement with the experimental data. For the correlation of systems containing tertiary amine molecules, binary interaction parameter had to be involved instead of hydrogen bonding parameters.

Original languageEnglish
Pages (from-to)833-837
Number of pages5
JournalKorean Journal of Chemical Engineering
Volume25
Issue number4
DOIs
Publication statusPublished - 2008 Jul 1

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Equations of state
Phase equilibria
Amines
Hydrogen bonds
Fluids
Hydrocarbons
Molecules
Temperature

Keywords

  • Amines
  • Correlation
  • Equation of state
  • Hydrocarbons
  • Hydrogen bonding
  • Lattice fluid
  • Vapor-liquid equilibrium

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Vapor-liquid equilibrium correlations for systems containing amines using a lattice fluid equation of state with hydrogen bonding. / Breitholz, Alexander; Yoo, Ki Pung; Lim, Jong Sung; Lee, Chul Soo; Kang, Jeong Won.

In: Korean Journal of Chemical Engineering, Vol. 25, No. 4, 01.07.2008, p. 833-837.

Research output: Contribution to journalArticle

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