Variations in electrical properties of Nb-doped SrTiO 3 with cation nonstoichiometry

Jung Ho Moon, Seong Ho Kim, Keun Il Park, Yoonho Kim, Keon Kim

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The influences of Sr/(Ti+Nb) ratios on the electrical properties of Nb-doped SrTiO 3 ceramics have been investigated. Regardless of Sr/(Ti+Nb) ratios, the appearance of non-linearity in the current-voltage characteristics was observed. When Sr/(Ti+Nb) ratio is lower than 1.000, the results acquired from impedance analysis revealed that the activation energies for carrier conduction were determined to be 0.83 eV in grains and 1.67 eV in grain boundaries. Otherwise, the specimens with Sr/(Ti+Nb) ≥ 1.004 showed energies of 0.80 eV in grains and 1.27 eV in grain boundaries. From these measured results, it was suggested that the activation energies, about 0.80 eV, measured in grains were originated from oxygen vacancies and the activation energies, 1.27 and 1.67 eV, measured in grain boundaries were from titanium and strontium vacancies, respectively.

Original languageEnglish
Title of host publicationFerroelectrics
Pages267-272
Number of pages6
Volume269
DOIs
Publication statusPublished - 2002 Jan 1

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials

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    Moon, J. H., Kim, S. H., Park, K. I., Kim, Y., & Kim, K. (2002). Variations in electrical properties of Nb-doped SrTiO 3 with cation nonstoichiometry In Ferroelectrics (Vol. 269, pp. 267-272) https://doi.org/10.1080/00150190211166