Voltammetric studies of thiacalix[4]arene and p-tert-butylthiacalix[4]arene and their analytical application

Tae Hyun Kim, Jae Kwang Lee, Ju Han Bok, Jong Seung Kim, Hasuck Kim

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

The electrochemical properties of thiacalix[4]arene (TCA) and p-tert-butylthiacalix[4]arene (BuTCA) in the presence of various metal ions were investigated by voltammetry in organic and aqueous acetonitrile solution (pH 8). Their behavior were closely related to the complex formation by entrapping metal ions into the cavity of host molecules, and were compared with the results with calix[4]arenes. Thiacalix[4]arenes showed better binding ability towards transition metal ions than alkali or alkaline earth metal ions.

Original languageEnglish
Pages (from-to)3759-3763
Number of pages5
JournalElectrochimica Acta
Volume49
Issue number22-23 SPEC. ISS.
DOIs
Publication statusPublished - 2004 Sep 15
Externally publishedYes

Fingerprint

Metal ions
Alkaline Earth Metals
Alkaline earth metals
Alkalies
Voltammetry
Acetonitrile
Electrochemical properties
Transition metals
Molecules
p-tert-butylthiacalix(4)arene
thiacalix(4)arene

Keywords

  • Calixarene
  • Cation recognition
  • Thiacalixarene
  • Transition metal ion
  • Voltammetry

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Analytical Chemistry
  • Electrochemistry

Cite this

Voltammetric studies of thiacalix[4]arene and p-tert-butylthiacalix[4]arene and their analytical application. / Kim, Tae Hyun; Lee, Jae Kwang; Bok, Ju Han; Kim, Jong Seung; Kim, Hasuck.

In: Electrochimica Acta, Vol. 49, No. 22-23 SPEC. ISS., 15.09.2004, p. 3759-3763.

Research output: Contribution to journalArticle

Kim, Tae Hyun ; Lee, Jae Kwang ; Bok, Ju Han ; Kim, Jong Seung ; Kim, Hasuck. / Voltammetric studies of thiacalix[4]arene and p-tert-butylthiacalix[4]arene and their analytical application. In: Electrochimica Acta. 2004 ; Vol. 49, No. 22-23 SPEC. ISS. pp. 3759-3763.
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