Water-soluble distyrylbenzene fluorophore and fluorescence behavior in a polymeric vesicle

Rati Ranjan Nayak, Han Young Woo

Research output: Contribution to journalArticle

Abstract

A vesicle forming polymer, poly(sodium acrylamidoundecanoate) (PSAU) and a water-soluble distyryl-benzene-based fluorophore, TPADSB-C were synthesized and characterized by using UV-vis and photoluminescence (PL) spectroscopy. An inter-chain vesicle formation of PSAU was observed at -0.01 g/L from N-phenyl naphthylamine fluorescence measurement with changing PSAU concentration in water. Above critical aggregation concentration of PSAU, optical properties of TPADSB-C were investigated to study the microenvironment modulation through dye incorporation in the polymeric vesicle. The emission of TPADSB-C in the presence of PSAU vesicles was blue-shifted and the PL quantum efficiency was increased to 90% due to the microenvironment (e.g. polarity) change in aqueous solution. This study shows that the polymeric vesicle containing molecular fluorophores has a great potential as an efficient, stable and biocompatible labeling tag in biological cell imaging.

Original languageEnglish
Pages (from-to)513-519
Number of pages7
JournalJournal of the Korean Chemical Society
Volume51
Issue number6
DOIs
Publication statusPublished - 2007 Dec 20

Keywords

  • Distyrylbenzene
  • Fluorescence
  • Microenvironment
  • Vesicle
  • Water-soluble chromophore

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Chemical Engineering (miscellaneous)

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